Enantioselective Friedel–Crafts reaction of indoles with arylidene malonates catalyzed by iPr-bisoxazoline–Cu(OTf)2

Jian Zhou; Yong Tang

doi:10.1039/b313197a

Enantioselective Friedel–Crafts reaction of indoles with arylidene malonates catalyzed by ⁱPr-bisoxazoline–Cu(OTf)₂

Jian Zhou
, Yong Tang^*

^*此作品的通讯作者

CAS - Shanghai Institute of Organic Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

115 引用（Scopus）

摘要

The cheap and simple ⁱPr-bisoxazoline–Cu(OTf)₂ proves to be an efficient catalyst in the asymmetric Friedel–Crafts reaction of indole with arylidene malonates. In ⁱBuOH, the S-enantiomer was obtained in up to 97% ee, while the opposite enantiomer was obtained in up to 78% ee in CH₂Cl₂ or TTCE.

源语言	英语
页（从-至）	432-433
页数	2
期刊	Chemical Communications
卷	4
期	4
DOI	https://doi.org/10.1039/b313197a
出版状态	已出版 - 2004
已对外发布	是

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10.1039/b313197a

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title = "Enantioselective Friedel–Crafts reaction of indoles with arylidene malonates catalyzed by iPr-bisoxazoline–Cu(OTf)2",

abstract = "The cheap and simple iPr-bisoxazoline–Cu(OTf)2 proves to be an efficient catalyst in the asymmetric Friedel–Crafts reaction of indole with arylidene malonates. In iBuOH, the S-enantiomer was obtained in up to 97\% ee, while the opposite enantiomer was obtained in up to 78\% ee in CH2Cl2 or TTCE.",

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year = "2004",

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AU - Tang, Yong

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Y1 - 2004

N2 - The cheap and simple iPr-bisoxazoline–Cu(OTf)2 proves to be an efficient catalyst in the asymmetric Friedel–Crafts reaction of indole with arylidene malonates. In iBuOH, the S-enantiomer was obtained in up to 97% ee, while the opposite enantiomer was obtained in up to 78% ee in CH2Cl2 or TTCE.

AB - The cheap and simple iPr-bisoxazoline–Cu(OTf)2 proves to be an efficient catalyst in the asymmetric Friedel–Crafts reaction of indole with arylidene malonates. In iBuOH, the S-enantiomer was obtained in up to 97% ee, while the opposite enantiomer was obtained in up to 78% ee in CH2Cl2 or TTCE.

UR - https://www.scopus.com/pages/publications/1442276308

U2 - 10.1039/b313197a

DO - 10.1039/b313197a

M3 - 文章

AN - SCOPUS:1442276308

SN - 1359-7345

VL - 4

SP - 432

EP - 433

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

Enantioselective Friedel–Crafts reaction of indoles with arylidene malonates catalyzed by iPr-bisoxazoline–Cu(OTf)2

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Enantioselective Friedel–Crafts reaction of indoles with arylidene malonates catalyzed by ⁱPr-bisoxazoline–Cu(OTf)₂