Enantioselective domino reaction of CO2, amines and allyl chlorides under iridium catalysis: Formation of allyl carbamates

Min Zhang; Xiaoming Zhao; Shengcai Zheng

doi:10.1039/c4cc00413b

Enantioselective domino reaction of CO₂, amines and allyl chlorides under iridium catalysis: Formation of allyl carbamates

Min Zhang
, Xiaoming Zhao^*
, Shengcai Zheng

^*此作品的通讯作者

Tongji University

科研成果: 期刊稿件 › 文章 › 同行评审

69 引用（Scopus）

摘要

The enantioselective domino reaction between CO₂ (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO₂. This journal is

源语言	英语
页（从-至）	4455-4458
页数	4
期刊	Chemical Communications
卷	50
期	34
DOI	https://doi.org/10.1039/c4cc00413b
出版状态	已出版 - 4 5月 2014
已对外发布	是

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abstract = "The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94\% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO2. This journal is",

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T2 - Formation of allyl carbamates

AU - Zhang, Min

AU - Zhao, Xiaoming

AU - Zheng, Shengcai

PY - 2014/5/4

Y1 - 2014/5/4

N2 - The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO2. This journal is

AB - The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO2. This journal is

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Enantioselective domino reaction of CO2, amines and allyl chlorides under iridium catalysis: Formation of allyl carbamates

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Enantioselective domino reaction of CO₂, amines and allyl chlorides under iridium catalysis: Formation of allyl carbamates