Enabling simultaneous redox transformation of toxic chromium(VI) and arsenic(III) in aqueous media—A review

Simultaneous conversion of most harmful As(III) and Cr(VI) to their less toxic counterparts is environmentally desirable and cost-effective. It has been confirmed that simultaneous oxidation of As(III) to As(V) and reduction of Cr(VI) to Cr(III) can occur via free radical or mediated electron transfer processes. While Cr(VI) is reduced by reacting with H^•, e_aq⁻, photoelectron directly or undergoing ligand exchange with H₂O₂ and SO₃²⁻, As(III) is oxidized by HO^•, SO₄^•−, O₂^•−, and holes (h⁺) in free radical process. The ability to concentrate Cr and As species on heterogeneous interface and conductivity determining the co-conversion efficiency in mediated electron transfer process. Acidity has positive effect on these co-conversion, while mediated electron transfer process is not much affected by dissolved oxygen (O₂). Organic compounds (e.g., oxalate, citrate and phenol) commonly favor Cr(VI) reduction and inhibit As(III) oxidation. To better understand the trends in the existing data and to identify the knowledge gaps, this review elaborates the complicated mechanisms for co-conversion of As(III) and Cr(VI) by various methods. Some challenges and prospects in this active field are also briefly discussed.