Electrochemical reduction of sulfoxides to thioethers with hydrosilanes catalyzed by a recyclable ionic liquid

Zhaoxin Wei; Ziren Chen; Fei Xue; Bin Wang; Yu Xia; Shaofeng Wu; Yonghong Zhang; Weiwei Jin; Xue Feng Jiang; Chenjiang Liu

doi:10.1039/d5gc05274b

Electrochemical reduction of sulfoxides to thioethers with hydrosilanes catalyzed by a recyclable ionic liquid

Zhaoxin Wei
, Ziren Chen
, Fei Xue
, Bin Wang
, Yu Xia
, Shaofeng Wu
, Yonghong Zhang
, Weiwei Jin
, Xue Feng Jiang^*
, Chenjiang Liu^*

^*此作品的通讯作者

化学与分子工程学院

Ministry of Education of the People's Republic of China
China Jiliang University
Xinjiang Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

The first electrochemical reduction of sulfoxides to thioethers has been achieved using a recyclable ionic liquid as both catalyst and electrolyte, without metal catalysts, stoichiometric redox reagents, or external electrolytes. The ionic liquid showed no significant loss of catalytic activity over six cycles. Various sulfoxides (32 examples) were efficiently reduced to the corresponding thioethers in up to 98% yield using hydrosilanes as the activating agent. Notably, the protocol exhibits robust scalability under optimized conditions.

源语言	英语
页（从-至）	132-137
页数	6
期刊	Green Chemistry
卷	28
期	1
DOI	https://doi.org/10.1039/d5gc05274b
出版状态	已出版 - 5 1月 2026

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title = "Electrochemical reduction of sulfoxides to thioethers with hydrosilanes catalyzed by a recyclable ionic liquid",

abstract = "The first electrochemical reduction of sulfoxides to thioethers has been achieved using a recyclable ionic liquid as both catalyst and electrolyte, without metal catalysts, stoichiometric redox reagents, or external electrolytes. The ionic liquid showed no significant loss of catalytic activity over six cycles. Various sulfoxides (32 examples) were efficiently reduced to the corresponding thioethers in up to 98\% yield using hydrosilanes as the activating agent. Notably, the protocol exhibits robust scalability under optimized conditions.",

author = "Zhaoxin Wei and Ziren Chen and Fei Xue and Bin Wang and Yu Xia and Shaofeng Wu and Yonghong Zhang and Weiwei Jin and Jiang, \{Xue Feng\} and Chenjiang Liu",

note = "Publisher Copyright: This journal is {\^A}{\textcopyright} The Royal Society of Chemistry, 2026",

year = "2026",

month = jan,

day = "5",

doi = "10.1039/d5gc05274b",

language = "英语",

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TY - JOUR

T1 - Electrochemical reduction of sulfoxides to thioethers with hydrosilanes catalyzed by a recyclable ionic liquid

AU - Wei, Zhaoxin

AU - Chen, Ziren

AU - Xue, Fei

AU - Wang, Bin

AU - Xia, Yu

AU - Wu, Shaofeng

AU - Zhang, Yonghong

AU - Jin, Weiwei

AU - Jiang, Xue Feng

AU - Liu, Chenjiang

PY - 2026/1/5

Y1 - 2026/1/5

N2 - The first electrochemical reduction of sulfoxides to thioethers has been achieved using a recyclable ionic liquid as both catalyst and electrolyte, without metal catalysts, stoichiometric redox reagents, or external electrolytes. The ionic liquid showed no significant loss of catalytic activity over six cycles. Various sulfoxides (32 examples) were efficiently reduced to the corresponding thioethers in up to 98% yield using hydrosilanes as the activating agent. Notably, the protocol exhibits robust scalability under optimized conditions.

AB - The first electrochemical reduction of sulfoxides to thioethers has been achieved using a recyclable ionic liquid as both catalyst and electrolyte, without metal catalysts, stoichiometric redox reagents, or external electrolytes. The ionic liquid showed no significant loss of catalytic activity over six cycles. Various sulfoxides (32 examples) were efficiently reduced to the corresponding thioethers in up to 98% yield using hydrosilanes as the activating agent. Notably, the protocol exhibits robust scalability under optimized conditions.

UR - https://www.scopus.com/pages/publications/105023560987

U2 - 10.1039/d5gc05274b

DO - 10.1039/d5gc05274b

M3 - 文章

AN - SCOPUS:105023560987

SN - 1463-9262

VL - 28

SP - 132

EP - 137

JO - Green Chemistry

JF - Green Chemistry

IS - 1

ER -

Electrochemical reduction of sulfoxides to thioethers with hydrosilanes catalyzed by a recyclable ionic liquid

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