Electrochemical carboxylation of cinnamate esters in MeCN

Huan Wang; Kai Zhang; Ying Zi Liu; Mei Yu Lin; Jia Xing Lu

doi:10.1016/j.tet.2007.10.104

Electrochemical carboxylation of cinnamate esters in MeCN

Huan Wang
, Kai Zhang
, Ying Zi Liu
, Mei Yu Lin
, Jia Xing Lu^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

44 引用（Scopus）

摘要

Electrochemical carboxylation of cinnamate esters has been carried out by cathodic reduction of C{double bond, long}C bond in an undivided cell equipped with Mg sacrificial anode and using MeCN saturated with CO₂ as solvent. The yields and the ratio of mono- and dicarboxylic acids are strongly affected by various factors: cathodic material, current, charge, and temperature. The highest yield (78.9%) was obtained starting from ethyl cinnamate. Cyclic voltammograms have been measured and reaction pathways have been proposed.

源语言	英语
页（从-至）	314-318
页数	5
期刊	Tetrahedron
卷	64
期	2
DOI	https://doi.org/10.1016/j.tet.2007.10.104
出版状态	已出版 - 7 1月 2008

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title = "Electrochemical carboxylation of cinnamate esters in MeCN",

abstract = "Electrochemical carboxylation of cinnamate esters has been carried out by cathodic reduction of C\{double bond, long\}C bond in an undivided cell equipped with Mg sacrificial anode and using MeCN saturated with CO2 as solvent. The yields and the ratio of mono- and dicarboxylic acids are strongly affected by various factors: cathodic material, current, charge, and temperature. The highest yield (78.9\%) was obtained starting from ethyl cinnamate. Cyclic voltammograms have been measured and reaction pathways have been proposed.",

keywords = "Carbon dioxide, Carboxylation, Cinnamate esters, Electrochemical",

author = "Huan Wang and Kai Zhang and Liu, \{Ying Zi\} and Lin, \{Mei Yu\} and Lu, \{Jia Xing\}",

year = "2008",

month = jan,

day = "7",

doi = "10.1016/j.tet.2007.10.104",

language = "英语",

volume = "64",

pages = "314--318",

journal = "Tetrahedron",

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TY - JOUR

T1 - Electrochemical carboxylation of cinnamate esters in MeCN

AU - Wang, Huan

AU - Zhang, Kai

AU - Liu, Ying Zi

AU - Lin, Mei Yu

AU - Lu, Jia Xing

PY - 2008/1/7

Y1 - 2008/1/7

N2 - Electrochemical carboxylation of cinnamate esters has been carried out by cathodic reduction of C{double bond, long}C bond in an undivided cell equipped with Mg sacrificial anode and using MeCN saturated with CO2 as solvent. The yields and the ratio of mono- and dicarboxylic acids are strongly affected by various factors: cathodic material, current, charge, and temperature. The highest yield (78.9%) was obtained starting from ethyl cinnamate. Cyclic voltammograms have been measured and reaction pathways have been proposed.

AB - Electrochemical carboxylation of cinnamate esters has been carried out by cathodic reduction of C{double bond, long}C bond in an undivided cell equipped with Mg sacrificial anode and using MeCN saturated with CO2 as solvent. The yields and the ratio of mono- and dicarboxylic acids are strongly affected by various factors: cathodic material, current, charge, and temperature. The highest yield (78.9%) was obtained starting from ethyl cinnamate. Cyclic voltammograms have been measured and reaction pathways have been proposed.

KW - Carbon dioxide

KW - Carboxylation

KW - Cinnamate esters

KW - Electrochemical

UR - https://www.scopus.com/pages/publications/36448988589

U2 - 10.1016/j.tet.2007.10.104

DO - 10.1016/j.tet.2007.10.104

M3 - 文章

AN - SCOPUS:36448988589

SN - 0040-4020

VL - 64

SP - 314

EP - 318

JO - Tetrahedron

JF - Tetrahedron

IS - 2

ER -

Electrochemical carboxylation of cinnamate esters in MeCN

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