Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst

Yueqin Cai; Ye Liu; Guohua Gao

doi:10.1007/s00706-007-0693-3

Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst

Yueqin Cai
, Ye Liu^*
, Guohua Gao

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride based on 1,4-diazabicyclo[2.2.2]octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.

源语言	英语
页（从-至）	1163-1166
页数	4
期刊	Monatshefte fur Chemie
卷	138
期	11
DOI	https://doi.org/10.1007/s00706-007-0693-3
出版状态	已出版 - 11月 2007

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title = "Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst",

abstract = "A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride based on 1,4-diazabicyclo[2.2.2]octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.",

keywords = "Acrylates, Aldehydes, Baylis-Hillman reaction, Catalysts, Homogeneous catalysis",

author = "Yueqin Cai and Ye Liu and Guohua Gao",

year = "2007",

month = nov,

doi = "10.1007/s00706-007-0693-3",

language = "英语",

volume = "138",

pages = "1163--1166",

journal = "Monatshefte fur Chemie",

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T1 - Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst

AU - Cai, Yueqin

AU - Liu, Ye

AU - Gao, Guohua

PY - 2007/11

Y1 - 2007/11

N2 - A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride based on 1,4-diazabicyclo[2.2.2]octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.

AB - A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride based on 1,4-diazabicyclo[2.2.2]octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.

KW - Acrylates

KW - Aldehydes

KW - Baylis-Hillman reaction

KW - Catalysts

KW - Homogeneous catalysis

UR - https://www.scopus.com/pages/publications/35648941288

U2 - 10.1007/s00706-007-0693-3

DO - 10.1007/s00706-007-0693-3

M3 - 文章

AN - SCOPUS:35648941288

SN - 0026-9247

VL - 138

SP - 1163

EP - 1166

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 11

ER -

Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst

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