Effect of rare earth additives on the microstructure and dielectric properties of 0.67Pb(Mg1/3Nb2/3)O3-0. 33PbTiO3 ceramics

Ni Zhong; Ping Hua Xiang; Da Zhi Sun; Xian Lin Dong

doi:10.1016/j.mseb.2004.09.030

Effect of rare earth additives on the microstructure and dielectric properties of 0.67Pb(Mg_1/3Nb_2/3)O₃-0. 33PbTiO₃ ceramics

Ni Zhong^*
, Ping Hua Xiang
, Da Zhi Sun
, Xian Lin Dong

^*此作品的通讯作者

CAS - Shanghai Institute of Ceramics
Nara Institute of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

43 引用（Scopus）

摘要

Microstructure and dielectric properties of relaxor ferroelectrics in the solid solution, formulated 0.67Pb(Mg_1/3Nb_2/3) O ₃-0.33PbTiO₃ + 2 mol% RE (RE = Sm, Nd, Yb or Ce), have been investigated. The effects of these dopants on microstructure, maximum dielectric constant (K_max) and degree of ordering, etc. have been studied. It was found that doping of Sm, Nd and Ce reduced K_max from 23924 to 14921, 13466 and 12511 respectively, while the doping of Yb increased K_max to 27759. The variation of K_max is analyzed according to grain size, domain structure and order-disorder behavior. Diffuseness of the phase transition is calculated to indicate order-disorder behavior, which is roughly opposite to that of K_max. The present results show that order-disorder behavior is the key factor on K_max of PMN-PT ceramics near morphotropic phase boundary.

源语言	英语
页（从-至）	140-145
页数	6
期刊	Materials Science and Engineering: B
卷	116
期	2
DOI	https://doi.org/10.1016/j.mseb.2004.09.030
出版状态	已出版 - 25 1月 2005
已对外发布	是

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title = "Effect of rare earth additives on the microstructure and dielectric properties of 0.67Pb(Mg1/3Nb2/3)O3-0. 33PbTiO3 ceramics",

abstract = "Microstructure and dielectric properties of relaxor ferroelectrics in the solid solution, formulated 0.67Pb(Mg1/3Nb2/3) O 3-0.33PbTiO3 + 2 mol\% RE (RE = Sm, Nd, Yb or Ce), have been investigated. The effects of these dopants on microstructure, maximum dielectric constant (Kmax) and degree of ordering, etc. have been studied. It was found that doping of Sm, Nd and Ce reduced Kmax from 23924 to 14921, 13466 and 12511 respectively, while the doping of Yb increased Kmax to 27759. The variation of Kmax is analyzed according to grain size, domain structure and order-disorder behavior. Diffuseness of the phase transition is calculated to indicate order-disorder behavior, which is roughly opposite to that of Kmax. The present results show that order-disorder behavior is the key factor on Kmax of PMN-PT ceramics near morphotropic phase boundary.",

keywords = "Dielectric properties, Diffuseness of the phase transition, Grain size",

author = "Ni Zhong and Xiang, \{Ping Hua\} and Sun, \{Da Zhi\} and Dong, \{Xian Lin\}",

year = "2005",

month = jan,

day = "25",

doi = "10.1016/j.mseb.2004.09.030",

language = "英语",

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TY - JOUR

T1 - Effect of rare earth additives on the microstructure and dielectric properties of 0.67Pb(Mg1/3Nb2/3)O3-0. 33PbTiO3 ceramics

AU - Zhong, Ni

AU - Xiang, Ping Hua

AU - Sun, Da Zhi

AU - Dong, Xian Lin

PY - 2005/1/25

Y1 - 2005/1/25

N2 - Microstructure and dielectric properties of relaxor ferroelectrics in the solid solution, formulated 0.67Pb(Mg1/3Nb2/3) O 3-0.33PbTiO3 + 2 mol% RE (RE = Sm, Nd, Yb or Ce), have been investigated. The effects of these dopants on microstructure, maximum dielectric constant (Kmax) and degree of ordering, etc. have been studied. It was found that doping of Sm, Nd and Ce reduced Kmax from 23924 to 14921, 13466 and 12511 respectively, while the doping of Yb increased Kmax to 27759. The variation of Kmax is analyzed according to grain size, domain structure and order-disorder behavior. Diffuseness of the phase transition is calculated to indicate order-disorder behavior, which is roughly opposite to that of Kmax. The present results show that order-disorder behavior is the key factor on Kmax of PMN-PT ceramics near morphotropic phase boundary.

AB - Microstructure and dielectric properties of relaxor ferroelectrics in the solid solution, formulated 0.67Pb(Mg1/3Nb2/3) O 3-0.33PbTiO3 + 2 mol% RE (RE = Sm, Nd, Yb or Ce), have been investigated. The effects of these dopants on microstructure, maximum dielectric constant (Kmax) and degree of ordering, etc. have been studied. It was found that doping of Sm, Nd and Ce reduced Kmax from 23924 to 14921, 13466 and 12511 respectively, while the doping of Yb increased Kmax to 27759. The variation of Kmax is analyzed according to grain size, domain structure and order-disorder behavior. Diffuseness of the phase transition is calculated to indicate order-disorder behavior, which is roughly opposite to that of Kmax. The present results show that order-disorder behavior is the key factor on Kmax of PMN-PT ceramics near morphotropic phase boundary.

KW - Dielectric properties

KW - Diffuseness of the phase transition

KW - Grain size

UR - https://www.scopus.com/pages/publications/20444391476

U2 - 10.1016/j.mseb.2004.09.030

DO - 10.1016/j.mseb.2004.09.030

M3 - 文章

AN - SCOPUS:20444391476

SN - 0921-5107

VL - 116

SP - 140

EP - 145

JO - Materials Science and Engineering: B

JF - Materials Science and Engineering: B

IS - 2

ER -

Effect of rare earth additives on the microstructure and dielectric properties of 0.67Pb(Mg1/3Nb2/3)O3-0. 33PbTiO3 ceramics

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Effect of rare earth additives on the microstructure and dielectric properties of 0.67Pb(Mg_1/3Nb_2/3)O₃-0. 33PbTiO₃ ceramics