Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

Cong Bin Ji; Yun Lin Liu; Xiao Li Zhao; Yin Long Guo; Hao Yang Wang; Jian Zhou

doi:10.1039/c2ob06746c

Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

Cong Bin Ji
, Yun Lin Liu
, Xiao Li Zhao
, Yin Long Guo^*
, Hao Yang Wang
, Jian Zhou

^*此作品的通讯作者

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

32 引用（Scopus）

摘要

We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.

源语言	英语
页（从-至）	1158-1161
页数	4
期刊	Organic and Biomolecular Chemistry
卷	10
期	6
DOI	https://doi.org/10.1039/c2ob06746c
出版状态	已出版 - 14 2月 2012

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10.1039/c2ob06746c

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abstract = "We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.",

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AU - Ji, Cong Bin

AU - Liu, Yun Lin

AU - Zhao, Xiao Li

AU - Guo, Yin Long

AU - Wang, Hao Yang

AU - Zhou, Jian

PY - 2012/2/14

Y1 - 2012/2/14

N2 - We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.

AB - We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.

UR - https://www.scopus.com/pages/publications/84862908458

U2 - 10.1039/c2ob06746c

DO - 10.1039/c2ob06746c

M3 - 文章

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AN - SCOPUS:84862908458

SN - 1477-0520

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EP - 1161

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

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ER -

Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

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