Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ2 C 1,N]palladium(II)}

Yankui Sang; Qiaomin Hong; Wenwei Qiu; Qiancai Liu; Fan Yang

doi:10.1107/S1600536810003569

Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ² C ¹,N]palladium(II)}

Yankui Sang
, Qiaomin Hong
, Wenwei Qiu
, Qiancai Liu
, Fan Yang^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

The title compound, [Pd₂(C₉H₁₁ClN) ₂Cl₂], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N - Pd - C - C - C). In the crystal structure, weak C - H ⋯Cl hydrogen bonds link the mol-ecules in rows.

源语言	英语
页（从-至）	m252
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	66
期	3
DOI	https://doi.org/10.1107/S1600536810003569
出版状态	已出版 - 2010

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10.1107/S1600536810003569

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引用此

@article{f8dfcdad55154bf79a0fd889ce3e7f14,

title = "Di -μ Chloridobis-\{[4-chloro-2-(dimethylaminomethyl)phenyl- κ2 C 1,N]palladium(II)\}",

abstract = "The title compound, [Pd2(C9H11ClN) 2Cl2], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N - Pd - C - C - C). In the crystal structure, weak C - H ⋯Cl hydrogen bonds link the mol-ecules in rows.",

keywords = "Data-to-parameter ratio = 19.5, Mean σ(C-C) = 0.005 {\AA}, R factor = 0.032, Single-crystal X-ray study, T = 296 K, WR factor = 0.087",

author = "Yankui Sang and Qiaomin Hong and Wenwei Qiu and Qiancai Liu and Fan Yang",

year = "2010",

doi = "10.1107/S1600536810003569",

language = "英语",

volume = "66",

pages = "m252",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "3",

}

TY - JOUR

T1 - Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ2 C 1,N]palladium(II)}

AU - Sang, Yankui

AU - Hong, Qiaomin

AU - Qiu, Wenwei

AU - Liu, Qiancai

AU - Yang, Fan

PY - 2010

Y1 - 2010

N2 - The title compound, [Pd2(C9H11ClN) 2Cl2], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N - Pd - C - C - C). In the crystal structure, weak C - H ⋯Cl hydrogen bonds link the mol-ecules in rows.

AB - The title compound, [Pd2(C9H11ClN) 2Cl2], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N - Pd - C - C - C). In the crystal structure, weak C - H ⋯Cl hydrogen bonds link the mol-ecules in rows.

KW - Data-to-parameter ratio = 19.5

KW - Mean σ(C-C) = 0.005 Å

KW - R factor = 0.032

KW - Single-crystal X-ray study

KW - T = 296 K

KW - WR factor = 0.087

UR - https://www.scopus.com/pages/publications/77949349400

U2 - 10.1107/S1600536810003569

DO - 10.1107/S1600536810003569

M3 - 文章

AN - SCOPUS:77949349400

SN - 1600-5368

VL - 66

SP - m252

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ2 C 1,N]palladium(II)}

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Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ² C ¹,N]palladium(II)}