Developing an ionic medium for ligandless-palladium-catalysed Suzuki and Heck couplings

Gang Zou; Zhiyong Wang; Junru Zhu; Jie Tang; Ming Y. He

doi:10.1016/S1381-1169(03)00428-X

Developing an ionic medium for ligandless-palladium-catalysed Suzuki and Heck couplings

Gang Zou^*
, Zhiyong Wang
, Junru Zhu
, Jie Tang
, Ming Y. He

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

72 引用（Scopus）

摘要

High-melting-point alkylammonium tetrafluoroborates melt with water or toluene to form biphasic mixtures at much lower temperatures than their normal melting points, thus could serve as green reaction media for Suzuki and Heck couplings. Advantages of using the aqueous-ammonium biphasic catalytic system include: (1) working well with a ligandless palladium catalyst, (2) solving the solubility problem of organic substrates and (3) simplifying work-up procedures for both separation of products and recycling of reaction media.

源语言	英语
页（从-至）	193-198
页数	6
期刊	Journal of Molecular Catalysis A: Chemical
卷	206
期	1-2
DOI	https://doi.org/10.1016/S1381-1169(03)00428-X
出版状态	已出版 - 1 10月 2003

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title = "Developing an ionic medium for ligandless-palladium-catalysed Suzuki and Heck couplings",

abstract = "High-melting-point alkylammonium tetrafluoroborates melt with water or toluene to form biphasic mixtures at much lower temperatures than their normal melting points, thus could serve as green reaction media for Suzuki and Heck couplings. Advantages of using the aqueous-ammonium biphasic catalytic system include: (1) working well with a ligandless palladium catalyst, (2) solving the solubility problem of organic substrates and (3) simplifying work-up procedures for both separation of products and recycling of reaction media.",

keywords = "Biphasic catalysis, Heck-coupling, Ligandless-catalyst, Molten salt, Suzuki-coupling",

author = "Gang Zou and Zhiyong Wang and Junru Zhu and Jie Tang and He, \{Ming Y.\}",

year = "2003",

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doi = "10.1016/S1381-1169(03)00428-X",

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T1 - Developing an ionic medium for ligandless-palladium-catalysed Suzuki and Heck couplings

AU - Zou, Gang

AU - Wang, Zhiyong

AU - Zhu, Junru

AU - Tang, Jie

AU - He, Ming Y.

PY - 2003/10/1

Y1 - 2003/10/1

N2 - High-melting-point alkylammonium tetrafluoroborates melt with water or toluene to form biphasic mixtures at much lower temperatures than their normal melting points, thus could serve as green reaction media for Suzuki and Heck couplings. Advantages of using the aqueous-ammonium biphasic catalytic system include: (1) working well with a ligandless palladium catalyst, (2) solving the solubility problem of organic substrates and (3) simplifying work-up procedures for both separation of products and recycling of reaction media.

AB - High-melting-point alkylammonium tetrafluoroborates melt with water or toluene to form biphasic mixtures at much lower temperatures than their normal melting points, thus could serve as green reaction media for Suzuki and Heck couplings. Advantages of using the aqueous-ammonium biphasic catalytic system include: (1) working well with a ligandless palladium catalyst, (2) solving the solubility problem of organic substrates and (3) simplifying work-up procedures for both separation of products and recycling of reaction media.

KW - Biphasic catalysis

KW - Heck-coupling

KW - Ligandless-catalyst

KW - Molten salt

KW - Suzuki-coupling

UR - https://www.scopus.com/pages/publications/0141425870

U2 - 10.1016/S1381-1169(03)00428-X

DO - 10.1016/S1381-1169(03)00428-X

M3 - 文章

AN - SCOPUS:0141425870

SN - 1381-1169

VL - 206

SP - 193

EP - 198

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Developing an ionic medium for ligandless-palladium-catalysed Suzuki and Heck couplings

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