摘要
A new family of 120 polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR ( 1H and 31P), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods.
| 源语言 | 英语 |
|---|---|
| 页(从-至) | 5981-5988 |
| 页数 | 8 |
| 期刊 | Tetrahedron |
| 卷 | 69 |
| 期 | 29 |
| DOI | |
| 出版状态 | 已出版 - 22 7月 2013 |
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