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Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly

  • Nai Wei Wu
  • , Quan Jie Li
  • , Jing Zhang
  • , Jiuming He
  • , Jiang Kun Ou-Yang
  • , Hongwei Tan
  • , Zeper Abliz
  • , Hai Bo Yang*
  • *此作品的通讯作者
  • East China Normal University
  • Beijing Normal University
  • Chinese Academy of Medical Sciences

科研成果: 期刊稿件文章同行评审

摘要

A new family of 120 polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR ( 1H and 31P), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods.

源语言英语
页(从-至)5981-5988
页数8
期刊Tetrahedron
69
29
DOI
出版状态已出版 - 22 7月 2013

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