Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions

Fan Yang; Yangming Zhang; Rui Zheng; Jie Tang; Mingyuan He

doi:10.1016/S0022-328X(02)01195-6

Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions

Fan Yang
, Yangming Zhang
, Rui Zheng
, Jie Tang^*
, Mingyuan He

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

44 引用（Scopus）

摘要

Cyclopalladated complexes of tertiary arylamines are reported in this paper as highly efficient catalysts for the Heck reactions of iodoarenes with methylacrylate. The monomeric complexes (2 and 4), which contain mixed phosphorous-nitrogen (P-N) donors, were found to be more active than the corresponding dimeric ones, which contain only single nitrogen donor. Palladium mirror was observed, indicating the involvement of classic Pd(0)/Pd(II) catalytic cycle using these cyclopalladated complexes.

源语言	英语
页（从-至）	146-148
页数	3
期刊	Journal of Organometallic Chemistry
卷	651
期	1-2
DOI	https://doi.org/10.1016/S0022-328X(02)01195-6
出版状态	已出版 - 15 5月 2002

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title = "Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions",

abstract = "Cyclopalladated complexes of tertiary arylamines are reported in this paper as highly efficient catalysts for the Heck reactions of iodoarenes with methylacrylate. The monomeric complexes (2 and 4), which contain mixed phosphorous-nitrogen (P-N) donors, were found to be more active than the corresponding dimeric ones, which contain only single nitrogen donor. Palladium mirror was observed, indicating the involvement of classic Pd(0)/Pd(II) catalytic cycle using these cyclopalladated complexes.",

keywords = "Cyclopalladated complex, Heck reaction, Palladium catalyst, Palladium mirror",

author = "Fan Yang and Yangming Zhang and Rui Zheng and Jie Tang and Mingyuan He",

year = "2002",

month = may,

day = "15",

doi = "10.1016/S0022-328X(02)01195-6",

language = "英语",

volume = "651",

pages = "146--148",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions

AU - Yang, Fan

AU - Zhang, Yangming

AU - Zheng, Rui

AU - Tang, Jie

AU - He, Mingyuan

PY - 2002/5/15

Y1 - 2002/5/15

N2 - Cyclopalladated complexes of tertiary arylamines are reported in this paper as highly efficient catalysts for the Heck reactions of iodoarenes with methylacrylate. The monomeric complexes (2 and 4), which contain mixed phosphorous-nitrogen (P-N) donors, were found to be more active than the corresponding dimeric ones, which contain only single nitrogen donor. Palladium mirror was observed, indicating the involvement of classic Pd(0)/Pd(II) catalytic cycle using these cyclopalladated complexes.

AB - Cyclopalladated complexes of tertiary arylamines are reported in this paper as highly efficient catalysts for the Heck reactions of iodoarenes with methylacrylate. The monomeric complexes (2 and 4), which contain mixed phosphorous-nitrogen (P-N) donors, were found to be more active than the corresponding dimeric ones, which contain only single nitrogen donor. Palladium mirror was observed, indicating the involvement of classic Pd(0)/Pd(II) catalytic cycle using these cyclopalladated complexes.

KW - Cyclopalladated complex

KW - Heck reaction

KW - Palladium catalyst

KW - Palladium mirror

UR - https://www.scopus.com/pages/publications/0037093134

U2 - 10.1016/S0022-328X(02)01195-6

DO - 10.1016/S0022-328X(02)01195-6

M3 - 文章

AN - SCOPUS:0037093134

SN - 0022-328X

VL - 651

SP - 146

EP - 148

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions

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