Cyclodextrin Rotaxane with Switchable Pirouetting

Qi Wei Zhang; Jaroslav Zajíček; Bradley D. Smith

doi:10.1021/acs.orglett.8b00655

Cyclodextrin Rotaxane with Switchable Pirouetting

Qi Wei Zhang
, Jaroslav Zajíček
, Bradley D. Smith^*

^*此作品的通讯作者

University of Notre Dame

科研成果: 期刊稿件 › 文章 › 同行评审

30 引用（Scopus）

摘要

A [1]rotaxane with two threaded α-cyclodextrin (α-CD) wheels was synthesized in 92% yield using a one-pot process at room temperature that employed spontaneous α-CD threading onto a 12-carbon alkyl chain in water followed by an oxime condensation reaction that attached two boronic acid-containing stopper groups. Rapid pirouetting of the threaded α-CD wheels around the encapsulated dumbbell was switched "ON" or "OFF" by the presence of chemical additives that controlled boronate ester bond formation between the interlocked components.

源语言	英语
页（从-至）	2096-2099
页数	4
期刊	Organic Letters
卷	20
期	7
DOI	https://doi.org/10.1021/acs.orglett.8b00655
出版状态	已出版 - 6 4月 2018
已对外发布	是

访问文件

10.1021/acs.orglett.8b00655

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{3aeea3bc7a0649a6b65cb1945e4e93a2,

title = "Cyclodextrin Rotaxane with Switchable Pirouetting",

abstract = "A [1]rotaxane with two threaded α-cyclodextrin (α-CD) wheels was synthesized in 92\% yield using a one-pot process at room temperature that employed spontaneous α-CD threading onto a 12-carbon alkyl chain in water followed by an oxime condensation reaction that attached two boronic acid-containing stopper groups. Rapid pirouetting of the threaded α-CD wheels around the encapsulated dumbbell was switched {"}ON{"} or {"}OFF{"} by the presence of chemical additives that controlled boronate ester bond formation between the interlocked components.",

author = "Zhang, \{Qi Wei\} and Jaroslav Zaj{\'i}{\v c}ek and Smith, \{Bradley D.\}",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = apr,

day = "6",

doi = "10.1021/acs.orglett.8b00655",

language = "英语",

volume = "20",

pages = "2096--2099",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - Cyclodextrin Rotaxane with Switchable Pirouetting

AU - Zhang, Qi Wei

AU - Zajíček, Jaroslav

AU - Smith, Bradley D.

PY - 2018/4/6

Y1 - 2018/4/6

N2 - A [1]rotaxane with two threaded α-cyclodextrin (α-CD) wheels was synthesized in 92% yield using a one-pot process at room temperature that employed spontaneous α-CD threading onto a 12-carbon alkyl chain in water followed by an oxime condensation reaction that attached two boronic acid-containing stopper groups. Rapid pirouetting of the threaded α-CD wheels around the encapsulated dumbbell was switched "ON" or "OFF" by the presence of chemical additives that controlled boronate ester bond formation between the interlocked components.

AB - A [1]rotaxane with two threaded α-cyclodextrin (α-CD) wheels was synthesized in 92% yield using a one-pot process at room temperature that employed spontaneous α-CD threading onto a 12-carbon alkyl chain in water followed by an oxime condensation reaction that attached two boronic acid-containing stopper groups. Rapid pirouetting of the threaded α-CD wheels around the encapsulated dumbbell was switched "ON" or "OFF" by the presence of chemical additives that controlled boronate ester bond formation between the interlocked components.

UR - https://www.scopus.com/pages/publications/85045135814

U2 - 10.1021/acs.orglett.8b00655

DO - 10.1021/acs.orglett.8b00655

M3 - 文章

C2 - 29542930

AN - SCOPUS:85045135814

SN - 1523-7060

VL - 20

SP - 2096

EP - 2099

JO - Organic Letters

JF - Organic Letters

IS - 7

ER -

Cyclodextrin Rotaxane with Switchable Pirouetting

摘要

访问文件

其它文件与链接

指纹

引用此