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Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

  • Qun Ye
  • , Jingjing Chang
  • , Kuo Wei Huang
  • , Xueliang Shi
  • , Jishan Wu
  • , Chunyan Chi*
  • *此作品的通讯作者
  • National University of Singapore
  • King Abdullah University of Science and Technology
  • Agency for Science, Technology and Research, Singapore

科研成果: 期刊稿件文章同行评审

摘要

Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method.

源语言英语
页(从-至)1194-1197
页数4
期刊Organic Letters
15
6
DOI
出版状态已出版 - 15 3月 2013
已对外发布

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