Crystal structure of borophosphate with 61 screw axis helices

Heng Zhen Shi; Yong Kui Shan; Li Yi Dai; Yu Yan Liu; Lin Hong Weng

Crystal structure of borophosphate with 6₁ screw axis helices

Heng Zhen Shi
, Yong Kui Shan^*
, Li Yi Dai
, Yu Yan Liu
, Lin Hong Weng

^*此作品的通讯作者

化学与分子工程学院

East China Normal University
Fudan University

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

A brilliant purple octahedral single crystal is hydrothermally synthesized by the reaction of CoCl₂·6H₂O, H₃BO ₃ and H₃PO₄ in NaOH aqueous solution of CH ₃(CH₂)₁₅N(CH₃)₃Br, and its crystal structure has been characterized by single-crystal X-ray diffraction. The compound, NaCo(H₂O)₂BP₂O ₈·H₂O (M_r = 336.72), belongs to hexagonal, space group P6₁22 with a = 9.447(5), c = 15.83(1) Å, V= 1223(1) Å³, D_c = 2.742 g/cm³, Z = 6, F(000) = 1002 and μ = 2.606 mm^-1. The three-dimensional framework in the compound is built up from the linkage tetrahedral ribbons, in which the BO₄ and PO₄ tetrahedra alternate with CoO₆ octahedra. The sodium ions and water molecules are located within the free thread of the helical ribbons.

源语言	英语
页（从-至）	391-394
页数	4
期刊	Jiegou Huaxue
卷	22
期	4
出版状态	已出版 - 2003

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引用此

@article{b0aae3712da94c8ab1cdb99d54310b51,

title = "Crystal structure of borophosphate with 61 screw axis helices",

abstract = "A brilliant purple octahedral single crystal is hydrothermally synthesized by the reaction of CoCl2·6H2O, H3BO 3 and H3PO4 in NaOH aqueous solution of CH 3(CH2)15N(CH3)3Br, and its crystal structure has been characterized by single-crystal X-ray diffraction. The compound, NaCo(H2O)2BP2O 8·H2O (Mr = 336.72), belongs to hexagonal, space group P6122 with a = 9.447(5), c = 15.83(1) {\AA}, V= 1223(1) {\AA}3, Dc = 2.742 g/cm3, Z = 6, F(000) = 1002 and μ = 2.606 mm-1. The three-dimensional framework in the compound is built up from the linkage tetrahedral ribbons, in which the BO4 and PO4 tetrahedra alternate with CoO6 octahedra. The sodium ions and water molecules are located within the free thread of the helical ribbons.",

keywords = "Borophosphate, Helice, Single crystal, Tetrahedra",

author = "Shi, \{Heng Zhen\} and Shan, \{Yong Kui\} and Dai, \{Li Yi\} and Liu, \{Yu Yan\} and Weng, \{Lin Hong\}",

year = "2003",

language = "英语",

volume = "22",

pages = "391--394",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "4",

}

TY - JOUR

T1 - Crystal structure of borophosphate with 61 screw axis helices

AU - Shi, Heng Zhen

AU - Shan, Yong Kui

AU - Dai, Li Yi

AU - Liu, Yu Yan

AU - Weng, Lin Hong

PY - 2003

Y1 - 2003

N2 - A brilliant purple octahedral single crystal is hydrothermally synthesized by the reaction of CoCl2·6H2O, H3BO 3 and H3PO4 in NaOH aqueous solution of CH 3(CH2)15N(CH3)3Br, and its crystal structure has been characterized by single-crystal X-ray diffraction. The compound, NaCo(H2O)2BP2O 8·H2O (Mr = 336.72), belongs to hexagonal, space group P6122 with a = 9.447(5), c = 15.83(1) Å, V= 1223(1) Å3, Dc = 2.742 g/cm3, Z = 6, F(000) = 1002 and μ = 2.606 mm-1. The three-dimensional framework in the compound is built up from the linkage tetrahedral ribbons, in which the BO4 and PO4 tetrahedra alternate with CoO6 octahedra. The sodium ions and water molecules are located within the free thread of the helical ribbons.

AB - A brilliant purple octahedral single crystal is hydrothermally synthesized by the reaction of CoCl2·6H2O, H3BO 3 and H3PO4 in NaOH aqueous solution of CH 3(CH2)15N(CH3)3Br, and its crystal structure has been characterized by single-crystal X-ray diffraction. The compound, NaCo(H2O)2BP2O 8·H2O (Mr = 336.72), belongs to hexagonal, space group P6122 with a = 9.447(5), c = 15.83(1) Å, V= 1223(1) Å3, Dc = 2.742 g/cm3, Z = 6, F(000) = 1002 and μ = 2.606 mm-1. The three-dimensional framework in the compound is built up from the linkage tetrahedral ribbons, in which the BO4 and PO4 tetrahedra alternate with CoO6 octahedra. The sodium ions and water molecules are located within the free thread of the helical ribbons.

KW - Borophosphate

KW - Helice

KW - Single crystal

KW - Tetrahedra

UR - https://www.scopus.com/pages/publications/0042885815

M3 - 文章

AN - SCOPUS:0042885815

SN - 0254-5861

VL - 22

SP - 391

EP - 394

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 4

ER -

Crystal structure of borophosphate with 61 screw axis helices

摘要

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Crystal structure of borophosphate with 6₁ screw axis helices