Cracking desulfurization of thiophene contained in hydrocarbons over zeolites

Jun Fu; Peng Wang; Ming Yuan He

Cracking desulfurization of thiophene contained in hydrocarbons over zeolites

Jun Fu^*
, Peng Wang
, Ming Yuan He

^*此作品的通讯作者

SINOPEC

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

The effect of different zeolites as catalysts, reaction conditions, and the type of hydrocarbons as co-reactants on the cracking-desulfurization of thiophene contained in hydrocarbons were investigated. Experimental results showed that the reaction conditions favoring the hydrogen transfer reaction also promoted the cracking desulfurization of thiophene. Hydrogen transfer through a bimolecular reaction between hydrocarbons and thiophene species seems to be the convincible reaction pathway for achieving desulfurization. The formation and decomposition of tetrahydrothiophene are the key steps in the reactions.

源语言	英语
页（从-至）	36-41
页数	6
期刊	Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)
卷	18
期	3
出版状态	已出版 - 6月 2002
已对外发布	是

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title = "Cracking desulfurization of thiophene contained in hydrocarbons over zeolites",

abstract = "The effect of different zeolites as catalysts, reaction conditions, and the type of hydrocarbons as co-reactants on the cracking-desulfurization of thiophene contained in hydrocarbons were investigated. Experimental results showed that the reaction conditions favoring the hydrogen transfer reaction also promoted the cracking desulfurization of thiophene. Hydrogen transfer through a bimolecular reaction between hydrocarbons and thiophene species seems to be the convincible reaction pathway for achieving desulfurization. The formation and decomposition of tetrahydrothiophene are the key steps in the reactions.",

keywords = "Catalytic cracking, Desulfurization, Hydrogen transfer, Thiophene, Zeolites",

author = "Jun Fu and Peng Wang and He, \{Ming Yuan\}",

year = "2002",

month = jun,

language = "英语",

volume = "18",

pages = "36--41",

journal = "Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)",

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TY - JOUR

T1 - Cracking desulfurization of thiophene contained in hydrocarbons over zeolites

AU - Fu, Jun

AU - Wang, Peng

AU - He, Ming Yuan

PY - 2002/6

Y1 - 2002/6

N2 - The effect of different zeolites as catalysts, reaction conditions, and the type of hydrocarbons as co-reactants on the cracking-desulfurization of thiophene contained in hydrocarbons were investigated. Experimental results showed that the reaction conditions favoring the hydrogen transfer reaction also promoted the cracking desulfurization of thiophene. Hydrogen transfer through a bimolecular reaction between hydrocarbons and thiophene species seems to be the convincible reaction pathway for achieving desulfurization. The formation and decomposition of tetrahydrothiophene are the key steps in the reactions.

AB - The effect of different zeolites as catalysts, reaction conditions, and the type of hydrocarbons as co-reactants on the cracking-desulfurization of thiophene contained in hydrocarbons were investigated. Experimental results showed that the reaction conditions favoring the hydrogen transfer reaction also promoted the cracking desulfurization of thiophene. Hydrogen transfer through a bimolecular reaction between hydrocarbons and thiophene species seems to be the convincible reaction pathway for achieving desulfurization. The formation and decomposition of tetrahydrothiophene are the key steps in the reactions.

KW - Catalytic cracking

KW - Desulfurization

KW - Hydrogen transfer

KW - Thiophene

KW - Zeolites

UR - https://www.scopus.com/pages/publications/0036622484

M3 - 文章

AN - SCOPUS:0036622484

SN - 1001-8719

VL - 18

SP - 36

EP - 41

JO - Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)

JF - Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)

IS - 3

ER -

Cracking desulfurization of thiophene contained in hydrocarbons over zeolites

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