Copper-catalyzed double N-alkenylation of amides: An efficient synthesis of di- or trisubstituted N-acylpyrroles

Xiyuan Yuan; Xiaobing Xu; Xiaobo Zhou; Jiwei Yuan; Lugen Mai; Yanzhong Li

doi:10.1021/jo062194s

Copper-catalyzed double N-alkenylation of amides: An efficient synthesis of di- or trisubstituted N-acylpyrroles

Xiyuan Yuan
, Xiaobing Xu
, Xiaobo Zhou
, Jiwei Yuan
, Lugen Mai
, Yanzhong Li^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

121 引用（Scopus）

摘要

(Chemical Equation Presented) An efficient copper-catalyzed double alkenylation of amides with (1Z,3Z)-1,4-diiodo-1,3-dienes is reported for the first time. The reactions proceed to afford di- or trisubstituted N-acylpyrroles in good to excellent yields using CuI as the catalyst, Cs₂CO ₃ as the base, and rac-trans-N,N′-dimethylcyclohexane-1,2- diamine as the ligand.

源语言	英语
页（从-至）	1510-1513
页数	4
期刊	Journal of Organic Chemistry
卷	72
期	4
DOI	https://doi.org/10.1021/jo062194s
出版状态	已出版 - 16 2月 2007

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abstract = "(Chemical Equation Presented) An efficient copper-catalyzed double alkenylation of amides with (1Z,3Z)-1,4-diiodo-1,3-dienes is reported for the first time. The reactions proceed to afford di- or trisubstituted N-acylpyrroles in good to excellent yields using CuI as the catalyst, Cs2CO 3 as the base, and rac-trans-N,N′-dimethylcyclohexane-1,2- diamine as the ligand.",

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T1 - Copper-catalyzed double N-alkenylation of amides

T2 - An efficient synthesis of di- or trisubstituted N-acylpyrroles

AU - Yuan, Xiyuan

AU - Xu, Xiaobing

AU - Zhou, Xiaobo

AU - Yuan, Jiwei

AU - Mai, Lugen

AU - Li, Yanzhong

PY - 2007/2/16

Y1 - 2007/2/16

N2 - (Chemical Equation Presented) An efficient copper-catalyzed double alkenylation of amides with (1Z,3Z)-1,4-diiodo-1,3-dienes is reported for the first time. The reactions proceed to afford di- or trisubstituted N-acylpyrroles in good to excellent yields using CuI as the catalyst, Cs2CO 3 as the base, and rac-trans-N,N′-dimethylcyclohexane-1,2- diamine as the ligand.

AB - (Chemical Equation Presented) An efficient copper-catalyzed double alkenylation of amides with (1Z,3Z)-1,4-diiodo-1,3-dienes is reported for the first time. The reactions proceed to afford di- or trisubstituted N-acylpyrroles in good to excellent yields using CuI as the catalyst, Cs2CO 3 as the base, and rac-trans-N,N′-dimethylcyclohexane-1,2- diamine as the ligand.

UR - https://www.scopus.com/pages/publications/33846972345

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DO - 10.1021/jo062194s

M3 - 文章

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SN - 0022-3263

VL - 72

SP - 1510

EP - 1513

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 4

ER -

Copper-catalyzed double N-alkenylation of amides: An efficient synthesis of di- or trisubstituted N-acylpyrroles

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