Copper-catalyzed chemoselective C-H functionalization/dearomatization sequence: direct access to indole-based spirocyclic scaffolds

Yuting Zhao; Xin Ji; Yuanjing Xiao; Xingxing Wu; Lu Liu

doi:10.1039/d5cc00594a

Copper-catalyzed chemoselective C-H functionalization/dearomatization sequence: direct access to indole-based spirocyclic scaffolds

Yuting Zhao
, Xin Ji
, Yuanjing Xiao^*
, Xingxing Wu^*
, Lu Liu^*

^*此作品的通讯作者

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

Herein, a copper-catalyzed intermolecular [4+1] spiroannulation of indoles with alkynyldiazoketones affording various indole-based spirocyclic molecules via a chemoselective C-H functionalization/dearomatization sequence was developed.

源语言	英语
页（从-至）	5162-5165
页数	4
期刊	Chemical Communications
卷	61
期	27
DOI	https://doi.org/10.1039/d5cc00594a
出版状态	已出版 - 5 3月 2025

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10.1039/d5cc00594a

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title = "Copper-catalyzed chemoselective C-H functionalization/dearomatization sequence: direct access to indole-based spirocyclic scaffolds",

abstract = "Herein, a copper-catalyzed intermolecular [4+1] spiroannulation of indoles with alkynyldiazoketones affording various indole-based spirocyclic molecules via a chemoselective C-H functionalization/dearomatization sequence was developed.",

author = "Yuting Zhao and Xin Ji and Yuanjing Xiao and Xingxing Wu and Lu Liu",

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year = "2025",

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T1 - Copper-catalyzed chemoselective C-H functionalization/dearomatization sequence

T2 - direct access to indole-based spirocyclic scaffolds

AU - Zhao, Yuting

AU - Ji, Xin

AU - Xiao, Yuanjing

AU - Wu, Xingxing

AU - Liu, Lu

PY - 2025/3/5

Y1 - 2025/3/5

N2 - Herein, a copper-catalyzed intermolecular [4+1] spiroannulation of indoles with alkynyldiazoketones affording various indole-based spirocyclic molecules via a chemoselective C-H functionalization/dearomatization sequence was developed.

AB - Herein, a copper-catalyzed intermolecular [4+1] spiroannulation of indoles with alkynyldiazoketones affording various indole-based spirocyclic molecules via a chemoselective C-H functionalization/dearomatization sequence was developed.

UR - https://www.scopus.com/pages/publications/86000600514

U2 - 10.1039/d5cc00594a

DO - 10.1039/d5cc00594a

M3 - 文章

C2 - 40070230

AN - SCOPUS:86000600514

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JO - Chemical Communications

JF - Chemical Communications

IS - 27

ER -

Copper-catalyzed chemoselective C-H functionalization/dearomatization sequence: direct access to indole-based spirocyclic scaffolds

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