Copper-catalysed: Ortho -selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters

Ben Ma; Zhiqiong Tang; Junliang Zhang; Lu Liu

doi:10.1039/d0cc04495d

Copper-catalysed: Ortho -selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters

Ben Ma
, Zhiqiong Tang
, Junliang Zhang^*
, Lu Liu^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University
Fudan University

科研成果: 期刊稿件 › 文章 › 同行评审

47 引用（Scopus）

摘要

Herein, we reported the first copper-catalyzed highly efficient C(sp2)-H functionalization of unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 efficiently promoted the highly chemo- and site-selective C-H bond functionalization under mild conditions, furnishing diverse phenol derivatives in moderate to excellent yields from readily available starting materials.

源语言	英语
页（从-至）	9485-9488
页数	4
期刊	Chemical Communications
卷	56
期	66
DOI	https://doi.org/10.1039/d0cc04495d
出版状态	已出版 - 25 8月 2020

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abstract = "Herein, we reported the first copper-catalyzed highly efficient C(sp2)-H functionalization of unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 efficiently promoted the highly chemo- and site-selective C-H bond functionalization under mild conditions, furnishing diverse phenol derivatives in moderate to excellent yields from readily available starting materials.",

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AU - Ma, Ben

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AU - Zhang, Junliang

AU - Liu, Lu

PY - 2020/8/25

Y1 - 2020/8/25

N2 - Herein, we reported the first copper-catalyzed highly efficient C(sp2)-H functionalization of unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 efficiently promoted the highly chemo- and site-selective C-H bond functionalization under mild conditions, furnishing diverse phenol derivatives in moderate to excellent yields from readily available starting materials.

AB - Herein, we reported the first copper-catalyzed highly efficient C(sp2)-H functionalization of unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 efficiently promoted the highly chemo- and site-selective C-H bond functionalization under mild conditions, furnishing diverse phenol derivatives in moderate to excellent yields from readily available starting materials.

UR - https://www.scopus.com/pages/publications/85089712603

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Copper-catalysed: Ortho -selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters

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