Coordination-driven self-assembly of charged and neutral dendritic tetrakis(ferrocenyl) rhomboids

Quan Jie Li; Guang Zhen Zhao; Li Jun Chen; Hongwei Tan; Cui Hong Wang; De Xian Wang; Danielle A. Lehman; David C. Muddiman; Hai Bo Yang

doi:10.1021/om3007932

Coordination-driven self-assembly of charged and neutral dendritic tetrakis(ferrocenyl) rhomboids

Quan Jie Li
, Guang Zhen Zhao
, Li Jun Chen
, Hongwei Tan^*
, Cui Hong Wang
, De Xian Wang
, Danielle A. Lehman
, David C. Muddiman
, Hai Bo Yang

^*此作品的通讯作者

化学与分子工程学院

Beijing Normal University
East China Normal University
CAS - Institute of Chemistry
North Carolina State University

科研成果: 期刊稿件 › 文章 › 同行评审

37 引用（Scopus）

摘要

By combining 60° bis(ferrocenyl) di-Pt(II) acceptors and the complementary 120° dipyridyl or dicarboxylate donors substituted with [G-1]-[G-3] Fréchet-type dendrons, self-assembly of a new series of charged or neutral dendritic tetrakis(ferrocenyl) rhomboids was realized under mild conditions in high yields, respectively. The structures of all difunctionalized rhomboids were characterized by multinuclear NMR ( ¹H and ³¹P), ESI-TOF-MS, CSI-TOF-MS, and elemental analysis. Moreover, their electrochemical behavior was studied through cyclic voltammetry investigations. Further insight into the structural characterization of all rhomboidal metallacycles, such as the shape and size, was obtained via molecular simulation by PM6 semiempirical molecular orbital methods.

源语言	英语
页（从-至）	7241-7247
页数	7
期刊	Organometallics
卷	31
期	20
DOI	https://doi.org/10.1021/om3007932
出版状态	已出版 - 22 10月 2012

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10.1021/om3007932

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title = "Coordination-driven self-assembly of charged and neutral dendritic tetrakis(ferrocenyl) rhomboids",

abstract = "By combining 60° bis(ferrocenyl) di-Pt(II) acceptors and the complementary 120° dipyridyl or dicarboxylate donors substituted with [G-1]-[G-3] Fr{\'e}chet-type dendrons, self-assembly of a new series of charged or neutral dendritic tetrakis(ferrocenyl) rhomboids was realized under mild conditions in high yields, respectively. The structures of all difunctionalized rhomboids were characterized by multinuclear NMR ( 1H and 31P), ESI-TOF-MS, CSI-TOF-MS, and elemental analysis. Moreover, their electrochemical behavior was studied through cyclic voltammetry investigations. Further insight into the structural characterization of all rhomboidal metallacycles, such as the shape and size, was obtained via molecular simulation by PM6 semiempirical molecular orbital methods.",

author = "Li, \{Quan Jie\} and Zhao, \{Guang Zhen\} and Chen, \{Li Jun\} and Hongwei Tan and Wang, \{Cui Hong\} and Wang, \{De Xian\} and Lehman, \{Danielle A.\} and Muddiman, \{David C.\} and Yang, \{Hai Bo\}",

year = "2012",

month = oct,

day = "22",

doi = "10.1021/om3007932",

language = "英语",

volume = "31",

pages = "7241--7247",

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T1 - Coordination-driven self-assembly of charged and neutral dendritic tetrakis(ferrocenyl) rhomboids

AU - Li, Quan Jie

AU - Zhao, Guang Zhen

AU - Chen, Li Jun

AU - Tan, Hongwei

AU - Wang, Cui Hong

AU - Wang, De Xian

AU - Lehman, Danielle A.

AU - Muddiman, David C.

AU - Yang, Hai Bo

PY - 2012/10/22

Y1 - 2012/10/22

N2 - By combining 60° bis(ferrocenyl) di-Pt(II) acceptors and the complementary 120° dipyridyl or dicarboxylate donors substituted with [G-1]-[G-3] Fréchet-type dendrons, self-assembly of a new series of charged or neutral dendritic tetrakis(ferrocenyl) rhomboids was realized under mild conditions in high yields, respectively. The structures of all difunctionalized rhomboids were characterized by multinuclear NMR ( 1H and 31P), ESI-TOF-MS, CSI-TOF-MS, and elemental analysis. Moreover, their electrochemical behavior was studied through cyclic voltammetry investigations. Further insight into the structural characterization of all rhomboidal metallacycles, such as the shape and size, was obtained via molecular simulation by PM6 semiempirical molecular orbital methods.

AB - By combining 60° bis(ferrocenyl) di-Pt(II) acceptors and the complementary 120° dipyridyl or dicarboxylate donors substituted with [G-1]-[G-3] Fréchet-type dendrons, self-assembly of a new series of charged or neutral dendritic tetrakis(ferrocenyl) rhomboids was realized under mild conditions in high yields, respectively. The structures of all difunctionalized rhomboids were characterized by multinuclear NMR ( 1H and 31P), ESI-TOF-MS, CSI-TOF-MS, and elemental analysis. Moreover, their electrochemical behavior was studied through cyclic voltammetry investigations. Further insight into the structural characterization of all rhomboidal metallacycles, such as the shape and size, was obtained via molecular simulation by PM6 semiempirical molecular orbital methods.

UR - https://www.scopus.com/pages/publications/84867833948

U2 - 10.1021/om3007932

DO - 10.1021/om3007932

M3 - 文章

AN - SCOPUS:84867833948

SN - 0276-7333

VL - 31

SP - 7241

EP - 7247

JO - Organometallics

JF - Organometallics

IS - 20

ER -

Coordination-driven self-assembly of charged and neutral dendritic tetrakis(ferrocenyl) rhomboids

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