Controllable and facile synthesis of CsPbBr₃-Cs₄PbBr₆ perovskite composites in pure polar solvent

Here, we present a single atomic supersaturated recrystallization method to synthesize the green-emitting CsPbBr₃-Cs₄PbBr₆ perovskite composites in solid state with the highest PLQY of 40.8% in pure polar solvent. The component, morphology, and optical properties of the microcrystals can be tuned by varying growth time, the content of ammonium bromide, and bromine source. The developed method provides a new route to large-scale synthesize high quality perovskite composites emitters for light-emitting diodes.