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Control of supramolecular rectangle self-assembly with a molecular template

  • Shan Shan Li
  • , Hui Juan Yan
  • , Li Jun Wan*
  • , Hai Bo Yang
  • , Brian H. Northrop
  • , Peter J. Stang
  • *此作品的通讯作者
  • CAS - Institute of Chemistry
  • University of Utah

科研成果: 期刊稿件文章同行评审

摘要

A facile method for controlling the self-assembly of supramolecular metallocycles on a highly oriented pyrolytic graphite (HOPG) surface is described. The process was demonstrated using 1,3,5-tris(10-carboxydecyloxy)benzene (TCDB), which self-assembles to form a stable monolayer with nanoscale cavities on HOPG, to template the deposition of supramolecular rectangles. Molecular distribution is controlled and monodispersion is achieved as the metallocycles self-organize into the cavities of the TCDB template.

源语言英语
页(从-至)9268-9269
页数2
期刊Journal of the American Chemical Society
129
30
DOI
出版状态已出版 - 1 8月 2007
已对外发布

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