摘要
A facile method for controlling the self-assembly of supramolecular metallocycles on a highly oriented pyrolytic graphite (HOPG) surface is described. The process was demonstrated using 1,3,5-tris(10-carboxydecyloxy)benzene (TCDB), which self-assembles to form a stable monolayer with nanoscale cavities on HOPG, to template the deposition of supramolecular rectangles. Molecular distribution is controlled and monodispersion is achieved as the metallocycles self-organize into the cavities of the TCDB template.
| 源语言 | 英语 |
|---|---|
| 页(从-至) | 9268-9269 |
| 页数 | 2 |
| 期刊 | Journal of the American Chemical Society |
| 卷 | 129 |
| 期 | 30 |
| DOI | |
| 出版状态 | 已出版 - 1 8月 2007 |
| 已对外发布 | 是 |
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