Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon

Li Jun Chen; Shangjun Chen; Yi Qin; Lin Xu; Guang Qiang Yin; Jun Long Zhu; Fan Fan Zhu; Wei Zheng; Xiaopeng Li; Hai Bo Yang

doi:10.1021/jacs.8b02386

Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon

Li Jun Chen
, Shangjun Chen
, Yi Qin
, Lin Xu
, Guang Qiang Yin
, Jun Long Zhu
, Fan Fan Zhu
, Wei Zheng
, Xiaopeng Li^*
, Hai Bo Yang

^*此作品的通讯作者

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

133 引用（Scopus）

摘要

The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, ¹O₂ generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.

源语言	英语
页（从-至）	5049-5052
页数	4
期刊	Journal of the American Chemical Society
卷	140
期	15
DOI	https://doi.org/10.1021/jacs.8b02386
出版状态	已出版 - 18 4月 2018

访问文件

10.1021/jacs.8b02386

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{d6a224a8d9854dcf8cc5d7e9af50d0d6,

title = "Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon",

abstract = "The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, 1O2 generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.",

author = "Chen, \{Li Jun\} and Shangjun Chen and Yi Qin and Lin Xu and Yin, \{Guang Qiang\} and Zhu, \{Jun Long\} and Zhu, \{Fan Fan\} and Wei Zheng and Xiaopeng Li and Yang, \{Hai Bo\}",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = apr,

day = "18",

doi = "10.1021/jacs.8b02386",

language = "英语",

volume = "140",

pages = "5049--5052",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon

AU - Chen, Li Jun

AU - Chen, Shangjun

AU - Qin, Yi

AU - Xu, Lin

AU - Yin, Guang Qiang

AU - Zhu, Jun Long

AU - Zhu, Fan Fan

AU - Zheng, Wei

AU - Li, Xiaopeng

AU - Yang, Hai Bo

PY - 2018/4/18

Y1 - 2018/4/18

N2 - The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, 1O2 generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.

AB - The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, 1O2 generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.

UR - https://www.scopus.com/pages/publications/85045626612

U2 - 10.1021/jacs.8b02386

DO - 10.1021/jacs.8b02386

M3 - 文章

C2 - 29625011

AN - SCOPUS:85045626612

SN - 0002-7863

VL - 140

SP - 5049

EP - 5052

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 15

ER -

Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon

摘要

访问文件

其它文件与链接

指纹

引用此