Competitive oxidation of N, N-diethylamine with H2O2 catalyzed by TS-1

Xiujuan Deng; Lu Shen; Shuo Zhang; Yueming Liu

doi:10.3724/SP.J.1088.2011.10543

Competitive oxidation of N, N-diethylamine with H₂O₂ catalyzed by TS-1

Xiujuan Deng
, Lu Shen
, Shuo Zhang
, Yueming Liu^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

Oxidation of N, N-diethylamine (DEA) to N, N-diethylhydroxylamine (DEHA) in the catalytic system of TS-1/H₂O₂ has been studied. The competitive reactions between the oxidation of DEA and DEHA were further investigated. The results suggested that the conversion of DEA and effective utilization of H₂O₂ can be increased dramatically when H₂O₂ was added dropwise, while the mole ratio of DEA/H₂O₂ greatly influenced the selectivity for DEHA. TS-1 can catalyze the oxidation of DEA, as well as the oxidation of DEHA.

源语言	英语
页（从-至）	1550-1556
页数	7
期刊	Chinese Journal of Catalysis
卷	32
期	9
DOI	https://doi.org/10.3724/SP.J.1088.2011.10543
出版状态	已出版 - 9月 2011

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10.3724/SP.J.1088.2011.10543

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@article{594805562bd9497296d65aab5d7e238a,

title = "Competitive oxidation of N, N-diethylamine with H2O2 catalyzed by TS-1",

abstract = "Oxidation of N, N-diethylamine (DEA) to N, N-diethylhydroxylamine (DEHA) in the catalytic system of TS-1/H2O2 has been studied. The competitive reactions between the oxidation of DEA and DEHA were further investigated. The results suggested that the conversion of DEA and effective utilization of H2O2 can be increased dramatically when H2O2 was added dropwise, while the mole ratio of DEA/H2O2 greatly influenced the selectivity for DEHA. TS-1 can catalyze the oxidation of DEA, as well as the oxidation of DEHA.",

keywords = "Hydrogen peroxide, N, N-diethylamine, N, N-diethylhydroxylamine, Oxidation, Titanium silicalite zeolite",

author = "Xiujuan Deng and Lu Shen and Shuo Zhang and Yueming Liu",

year = "2011",

month = sep,

doi = "10.3724/SP.J.1088.2011.10543",

language = "英语",

volume = "32",

pages = "1550--1556",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

publisher = "Science Press ",

number = "9",

}

TY - JOUR

T1 - Competitive oxidation of N, N-diethylamine with H2O2 catalyzed by TS-1

AU - Deng, Xiujuan

AU - Shen, Lu

AU - Zhang, Shuo

AU - Liu, Yueming

PY - 2011/9

Y1 - 2011/9

N2 - Oxidation of N, N-diethylamine (DEA) to N, N-diethylhydroxylamine (DEHA) in the catalytic system of TS-1/H2O2 has been studied. The competitive reactions between the oxidation of DEA and DEHA were further investigated. The results suggested that the conversion of DEA and effective utilization of H2O2 can be increased dramatically when H2O2 was added dropwise, while the mole ratio of DEA/H2O2 greatly influenced the selectivity for DEHA. TS-1 can catalyze the oxidation of DEA, as well as the oxidation of DEHA.

AB - Oxidation of N, N-diethylamine (DEA) to N, N-diethylhydroxylamine (DEHA) in the catalytic system of TS-1/H2O2 has been studied. The competitive reactions between the oxidation of DEA and DEHA were further investigated. The results suggested that the conversion of DEA and effective utilization of H2O2 can be increased dramatically when H2O2 was added dropwise, while the mole ratio of DEA/H2O2 greatly influenced the selectivity for DEHA. TS-1 can catalyze the oxidation of DEA, as well as the oxidation of DEHA.

KW - Hydrogen peroxide

KW - N, N-diethylamine

KW - N, N-diethylhydroxylamine

KW - Oxidation

KW - Titanium silicalite zeolite

UR - https://www.scopus.com/pages/publications/80054780344

U2 - 10.3724/SP.J.1088.2011.10543

DO - 10.3724/SP.J.1088.2011.10543

M3 - 文章

AN - SCOPUS:80054780344

SN - 1872-2067

VL - 32

SP - 1550

EP - 1556

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 9

ER -

Competitive oxidation of N, N-diethylamine with H2O2 catalyzed by TS-1

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Competitive oxidation of N, N-diethylamine with H₂O₂ catalyzed by TS-1