Cesium carbonate mediated borylation of aryl iodides with diboron in methanol

Jieming Zhang; Hai Hong Wu; Junliang Zhang

doi:10.1002/ejoc.201300829

Cesium carbonate mediated borylation of aryl iodides with diboron in methanol

Jieming Zhang
, Hai Hong Wu^*
, Junliang Zhang

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

68 引用（Scopus）

摘要

Herein we describe the unexpected borylation of aryl iodides promoted by a Cs₂CO₃ and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.

源语言	英语
页（从-至）	6263-6266
页数	4
期刊	European Journal of Organic Chemistry
期	28
DOI	https://doi.org/10.1002/ejoc.201300829
出版状态	已出版 - 10月 2013

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@article{c4fbf234844041278a0ee17db92c7b02,

title = "Cesium carbonate mediated borylation of aryl iodides with diboron in methanol",

abstract = "Herein we describe the unexpected borylation of aryl iodides promoted by a Cs2CO3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.",

keywords = "Boron, Cesium, Copper, Lewis bases, Transition metals",

author = "Jieming Zhang and Wu, \{Hai Hong\} and Junliang Zhang",

year = "2013",

month = oct,

doi = "10.1002/ejoc.201300829",

language = "英语",

pages = "6263--6266",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-VCH Verlag",

number = "28",

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TY - JOUR

T1 - Cesium carbonate mediated borylation of aryl iodides with diboron in methanol

AU - Zhang, Jieming

AU - Wu, Hai Hong

AU - Zhang, Junliang

PY - 2013/10

Y1 - 2013/10

N2 - Herein we describe the unexpected borylation of aryl iodides promoted by a Cs2CO3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.

AB - Herein we describe the unexpected borylation of aryl iodides promoted by a Cs2CO3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.

KW - Boron

KW - Cesium

KW - Copper

KW - Lewis bases

KW - Transition metals

UR - https://www.scopus.com/pages/publications/84884902694

U2 - 10.1002/ejoc.201300829

DO - 10.1002/ejoc.201300829

M3 - 文章

AN - SCOPUS:84884902694

SN - 1434-193X

SP - 6263

EP - 6266

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 28

ER -

Cesium carbonate mediated borylation of aryl iodides with diboron in methanol

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