Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption

Minghong Zhou; Zidong He; Tianqi Wang; Yang Xu; Wei Yu; Buyin Shi; Kun Huang

doi:10.1016/j.micromeso.2018.08.005

Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption

Minghong Zhou
, Zidong He
, Tianqi Wang
, Yang Xu
, Wei Yu
, Buyin Shi
, Kun Huang^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

Carboxyl group functionalized hollow microporous organic nanospheres (HMONs-COOH) were successfully synthesized by hyper-crosslinking reaction between polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and 2,4,6-tris(bromomethyl)mesitylene as well as subsequent alkaline KMnO₄ oxidation. The synthesized HMONs-COOH possess the high special surface area, robust organic framework and hierarchically porous structure, which shows highly catalytic activity in the Friedel-Crafts alkylation of indole with aldehydes and outstanding adsorption efficiency toward cationic dyes.

源语言	英语
页（从-至）	245-250
页数	6
期刊	Microporous and Mesoporous Materials
卷	274
DOI	https://doi.org/10.1016/j.micromeso.2018.08.005
出版状态	已出版 - 15 1月 2019

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@article{376cad93941543ccbe4e4593f45e7bb8,

title = "Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption",

abstract = "Carboxyl group functionalized hollow microporous organic nanospheres (HMONs-COOH) were successfully synthesized by hyper-crosslinking reaction between polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and 2,4,6-tris(bromomethyl)mesitylene as well as subsequent alkaline KMnO4 oxidation. The synthesized HMONs-COOH possess the high special surface area, robust organic framework and hierarchically porous structure, which shows highly catalytic activity in the Friedel-Crafts alkylation of indole with aldehydes and outstanding adsorption efficiency toward cationic dyes.",

keywords = "Adsorption, Carboxyl group, Diblock copolymers, Friedel-crafts alkylation, Hollow microporous organic nanospheres, Hyper-crosslinking",

author = "Minghong Zhou and Zidong He and Tianqi Wang and Yang Xu and Wei Yu and Buyin Shi and Kun Huang",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2019",

month = jan,

day = "15",

doi = "10.1016/j.micromeso.2018.08.005",

language = "英语",

volume = "274",

pages = "245--250",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption

AU - Zhou, Minghong

AU - He, Zidong

AU - Wang, Tianqi

AU - Xu, Yang

AU - Yu, Wei

AU - Shi, Buyin

AU - Huang, Kun

PY - 2019/1/15

Y1 - 2019/1/15

N2 - Carboxyl group functionalized hollow microporous organic nanospheres (HMONs-COOH) were successfully synthesized by hyper-crosslinking reaction between polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and 2,4,6-tris(bromomethyl)mesitylene as well as subsequent alkaline KMnO4 oxidation. The synthesized HMONs-COOH possess the high special surface area, robust organic framework and hierarchically porous structure, which shows highly catalytic activity in the Friedel-Crafts alkylation of indole with aldehydes and outstanding adsorption efficiency toward cationic dyes.

AB - Carboxyl group functionalized hollow microporous organic nanospheres (HMONs-COOH) were successfully synthesized by hyper-crosslinking reaction between polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and 2,4,6-tris(bromomethyl)mesitylene as well as subsequent alkaline KMnO4 oxidation. The synthesized HMONs-COOH possess the high special surface area, robust organic framework and hierarchically porous structure, which shows highly catalytic activity in the Friedel-Crafts alkylation of indole with aldehydes and outstanding adsorption efficiency toward cationic dyes.

KW - Adsorption

KW - Carboxyl group

KW - Diblock copolymers

KW - Friedel-crafts alkylation

KW - Hollow microporous organic nanospheres

KW - Hyper-crosslinking

UR - https://www.scopus.com/pages/publications/85051262473

U2 - 10.1016/j.micromeso.2018.08.005

DO - 10.1016/j.micromeso.2018.08.005

M3 - 文章

AN - SCOPUS:85051262473

SN - 1387-1811

VL - 274

SP - 245

EP - 250

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption

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