Base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines

Qiongwen Kang; Mengdan Wang; Zongkang Wang; Lu Cheng; Yilin Zhu; Chengyu Wang; Yanzhong Li

doi:10.1039/d3qo00818e

Base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines

Qiongwen Kang
, Mengdan Wang
, Zongkang Wang
, Lu Cheng
, Yilin Zhu
, Chengyu Wang^*
, Yanzhong Li^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University
Linyi University

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

A base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines under mild conditions has been developed. This is the first example of a transition-metal free ring-expansion reaction of indolones via the selective insertion of alkynoates into the C2-N1 bond. The process achieved the cleavage of one C-N bond and three C-C bonds, and the formation of one C-N and three C-C bonds in one step.

源语言	英语
页（从-至）	5205-5209
页数	5
期刊	Organic Chemistry Frontiers
卷	10
期	20
DOI	https://doi.org/10.1039/d3qo00818e
出版状态	已出版 - 5 9月 2023

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title = "Base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines",

abstract = "A base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines under mild conditions has been developed. This is the first example of a transition-metal free ring-expansion reaction of indolones via the selective insertion of alkynoates into the C2-N1 bond. The process achieved the cleavage of one C-N bond and three C-C bonds, and the formation of one C-N and three C-C bonds in one step.",

author = "Qiongwen Kang and Mengdan Wang and Zongkang Wang and Lu Cheng and Yilin Zhu and Chengyu Wang and Yanzhong Li",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

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doi = "10.1039/d3qo00818e",

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TY - JOUR

T1 - Base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines

AU - Kang, Qiongwen

AU - Wang, Mengdan

AU - Wang, Zongkang

AU - Cheng, Lu

AU - Zhu, Yilin

AU - Wang, Chengyu

AU - Li, Yanzhong

PY - 2023/9/5

Y1 - 2023/9/5

N2 - A base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines under mild conditions has been developed. This is the first example of a transition-metal free ring-expansion reaction of indolones via the selective insertion of alkynoates into the C2-N1 bond. The process achieved the cleavage of one C-N bond and three C-C bonds, and the formation of one C-N and three C-C bonds in one step.

AB - A base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines under mild conditions has been developed. This is the first example of a transition-metal free ring-expansion reaction of indolones via the selective insertion of alkynoates into the C2-N1 bond. The process achieved the cleavage of one C-N bond and three C-C bonds, and the formation of one C-N and three C-C bonds in one step.

UR - https://www.scopus.com/pages/publications/85171672124

U2 - 10.1039/d3qo00818e

DO - 10.1039/d3qo00818e

M3 - 文章

AN - SCOPUS:85171672124

SN - 2052-4110

VL - 10

SP - 5205

EP - 5209

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 20

ER -

Base-promoted selective C2-N1 ring-expansion reaction of indolones toward substituted quinolines

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