Asymmetric synthesis and biosynthetic implications of (+)-fusarisetin A

Jun Yin; Cheng Wang; Lili Kong; Shujun Cai; Shuanhu Gao

doi:10.1002/anie.201202455

Asymmetric synthesis and biosynthetic implications of (+)-fusarisetin A

Jun Yin
, Cheng Wang
, Lili Kong
, Shujun Cai
, Shuanhu Gao^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

85 引用（Scopus）

摘要

Starting from equisetin, the asymmetric synthesis of (+)-fusarisetin A has been accomplished in a one-pot transformation including a biomimetic oxidation and an intramolecular Diels-Alder/Roskamp reaction. Peroxyfusarisetin is proposed as a plausible biosynthetic intermediate based on studies of the oxidation of equisetin.

源语言	英语
页（从-至）	7786-7789
页数	4
期刊	Angewandte Chemie - International Edition
卷	51
期	31
DOI	https://doi.org/10.1002/anie.201202455
出版状态	已出版 - 27 7月 2012

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abstract = "Starting from equisetin, the asymmetric synthesis of (+)-fusarisetin A has been accomplished in a one-pot transformation including a biomimetic oxidation and an intramolecular Diels-Alder/Roskamp reaction. Peroxyfusarisetin is proposed as a plausible biosynthetic intermediate based on studies of the oxidation of equisetin.",

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author = "Jun Yin and Cheng Wang and Lili Kong and Shujun Cai and Shuanhu Gao",

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AU - Yin, Jun

AU - Wang, Cheng

AU - Kong, Lili

AU - Cai, Shujun

AU - Gao, Shuanhu

PY - 2012/7/27

Y1 - 2012/7/27

N2 - Starting from equisetin, the asymmetric synthesis of (+)-fusarisetin A has been accomplished in a one-pot transformation including a biomimetic oxidation and an intramolecular Diels-Alder/Roskamp reaction. Peroxyfusarisetin is proposed as a plausible biosynthetic intermediate based on studies of the oxidation of equisetin.

AB - Starting from equisetin, the asymmetric synthesis of (+)-fusarisetin A has been accomplished in a one-pot transformation including a biomimetic oxidation and an intramolecular Diels-Alder/Roskamp reaction. Peroxyfusarisetin is proposed as a plausible biosynthetic intermediate based on studies of the oxidation of equisetin.

KW - biosynthesis

KW - natural products

KW - peroxides

KW - radical reactions

KW - total synthesis

UR - https://www.scopus.com/pages/publications/84864403252

U2 - 10.1002/anie.201202455

DO - 10.1002/anie.201202455

M3 - 文章

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AN - SCOPUS:84864403252

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

Asymmetric synthesis and biosynthetic implications of (+)-fusarisetin A

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