Asymmetric sequential Au(i)/chiral tertiary amine catalysis: An enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles

Yu Lei Zhao; Zhong Yan Cao; Xing Ping Zeng; Jia Meng Shi; Yi Hua Yu; Jian Zhou

doi:10.1039/c6cc00333h

Asymmetric sequential Au(i)/chiral tertiary amine catalysis: An enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles

Yu Lei Zhao
, Zhong Yan Cao
, Xing Ping Zeng
, Jia Meng Shi
, Yi Hua Yu
, Jian Zhou^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University
CAS - Shanghai Institute of Organic Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

61 引用（Scopus）

摘要

An unprecedented sequential gold-catalyzed enone-formation and bifunctional tertiary amine mediated asymmetric cyanosilylation reaction is developed, allowing the highly enantioselective synthesis of 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN).

源语言	英语
页（从-至）	3943-3946
页数	4
期刊	Chemical Communications
卷	52
期	20
DOI	https://doi.org/10.1039/c6cc00333h
出版状态	已出版 - 2016

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10.1039/c6cc00333h

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title = "Asymmetric sequential Au(i)/chiral tertiary amine catalysis: An enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles",

abstract = "An unprecedented sequential gold-catalyzed enone-formation and bifunctional tertiary amine mediated asymmetric cyanosilylation reaction is developed, allowing the highly enantioselective synthesis of 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN).",

author = "Zhao, \{Yu Lei\} and Cao, \{Zhong Yan\} and Zeng, \{Xing Ping\} and Shi, \{Jia Meng\} and Yu, \{Yi Hua\} and Jian Zhou",

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year = "2016",

doi = "10.1039/c6cc00333h",

language = "英语",

volume = "52",

pages = "3943--3946",

journal = "Chemical Communications",

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T1 - Asymmetric sequential Au(i)/chiral tertiary amine catalysis

T2 - An enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles

AU - Zhao, Yu Lei

AU - Cao, Zhong Yan

AU - Zeng, Xing Ping

AU - Shi, Jia Meng

AU - Yu, Yi Hua

AU - Zhou, Jian

PY - 2016

Y1 - 2016

N2 - An unprecedented sequential gold-catalyzed enone-formation and bifunctional tertiary amine mediated asymmetric cyanosilylation reaction is developed, allowing the highly enantioselective synthesis of 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN).

AB - An unprecedented sequential gold-catalyzed enone-formation and bifunctional tertiary amine mediated asymmetric cyanosilylation reaction is developed, allowing the highly enantioselective synthesis of 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN).

UR - https://www.scopus.com/pages/publications/84959493411

U2 - 10.1039/c6cc00333h

DO - 10.1039/c6cc00333h

M3 - 文章

AN - SCOPUS:84959493411

SN - 1359-7345

VL - 52

SP - 3943

EP - 3946

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Asymmetric sequential Au(i)/chiral tertiary amine catalysis: An enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles

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