Asymmetric hydrogenation of α- Or β-acyloxy α,β- unsaturated phosphonates catalyzed by a Rh(i) complex of monodentate phosphoramidite

Jinzhu Zhang; Kaiwu Dong; Zheng Wang; Kuiling Ding

doi:10.1039/c1ob06835k

Asymmetric hydrogenation of α- Or β-acyloxy α,β- unsaturated phosphonates catalyzed by a Rh(i) complex of monodentate phosphoramidite

Jinzhu Zhang
, Kaiwu Dong
, Zheng Wang
, Kuiling Ding^*

^*此作品的通讯作者

CAS - Shanghai Institute of Organic Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

26 引用（Scopus）

摘要

The Rh(i) complex of a monodentate phosphoramidite bearing a primary amine moiety (DpenPhos) has been disclosed to be highly efficient for the asymmetric hydrogenation of a variety of α- or β-acyloxy α,β- unsaturated phosphonates, providing the corresponding biologically important chiral α- or β-hydroxy phosphonic acid derivatives with excellent enantioselectivities (90->99% ee).

源语言	英语
页（从-至）	1598-1601
页数	4
期刊	Organic and Biomolecular Chemistry
卷	10
期	8
DOI	https://doi.org/10.1039/c1ob06835k
出版状态	已出版 - 28 2月 2012
已对外发布	是

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abstract = "The Rh(i) complex of a monodentate phosphoramidite bearing a primary amine moiety (DpenPhos) has been disclosed to be highly efficient for the asymmetric hydrogenation of a variety of α- or β-acyloxy α,β- unsaturated phosphonates, providing the corresponding biologically important chiral α- or β-hydroxy phosphonic acid derivatives with excellent enantioselectivities (90->99\% ee).",

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AU - Zhang, Jinzhu

AU - Dong, Kaiwu

AU - Wang, Zheng

AU - Ding, Kuiling

PY - 2012/2/28

Y1 - 2012/2/28

N2 - The Rh(i) complex of a monodentate phosphoramidite bearing a primary amine moiety (DpenPhos) has been disclosed to be highly efficient for the asymmetric hydrogenation of a variety of α- or β-acyloxy α,β- unsaturated phosphonates, providing the corresponding biologically important chiral α- or β-hydroxy phosphonic acid derivatives with excellent enantioselectivities (90->99% ee).

AB - The Rh(i) complex of a monodentate phosphoramidite bearing a primary amine moiety (DpenPhos) has been disclosed to be highly efficient for the asymmetric hydrogenation of a variety of α- or β-acyloxy α,β- unsaturated phosphonates, providing the corresponding biologically important chiral α- or β-hydroxy phosphonic acid derivatives with excellent enantioselectivities (90->99% ee).

UR - https://www.scopus.com/pages/publications/84863115613

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DO - 10.1039/c1ob06835k

M3 - 文章

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AN - SCOPUS:84863115613

SN - 1477-0520

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JF - Organic and Biomolecular Chemistry

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ER -

Asymmetric hydrogenation of α- Or β-acyloxy α,β- unsaturated phosphonates catalyzed by a Rh(i) complex of monodentate phosphoramidite

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