Arylamine-catalyzed enamine formation: Cooperative catalysis with arylamines and acids

Yongming Deng; Lu Liu; Ryan G. Sarkisian; Kraig Wheeler; Hong Wang; Zhenghu Xu

doi:10.1002/anie.201209268

Arylamine-catalyzed enamine formation: Cooperative catalysis with arylamines and acids

Yongming Deng
, Lu Liu
, Ryan G. Sarkisian
, Kraig Wheeler
, Hong Wang^*
, Zhenghu Xu

^*此作品的通讯作者

Miami University
Eastern Illinois University
Shandong University

科研成果: 期刊稿件 › 文章 › 同行评审

87 引用（Scopus）

摘要

Powerful combination: Arylamines and metal Lewis acids are used as catalysts in the highly chemo- and enantioselective three-component inverse-electron-demand aza-Diels-Alder reaction of cyclic ketones with enones. The enantioselectivity is introduced by a simple chiral anion (see scheme). Arylamines can also serve as effective enamine catalysts in combination with either a metal Lewis acid or a Brønsted acid.

源语言	英语
页（从-至）	3663-3667
页数	5
期刊	Angewandte Chemie - International Edition
卷	52
期	13
DOI	https://doi.org/10.1002/anie.201209268
出版状态	已出版 - 25 3月 2013
已对外发布	是

访问文件

10.1002/anie.201209268

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{23353d65bb8142a793ef416c35d58e57,

title = "Arylamine-catalyzed enamine formation: Cooperative catalysis with arylamines and acids",

abstract = "Powerful combination: Arylamines and metal Lewis acids are used as catalysts in the highly chemo- and enantioselective three-component inverse-electron-demand aza-Diels-Alder reaction of cyclic ketones with enones. The enantioselectivity is introduced by a simple chiral anion (see scheme). Arylamines can also serve as effective enamine catalysts in combination with either a metal Lewis acid or a Br{\o}nsted acid.",

keywords = "Lewis acids, aza-Diels-Alder reactions, cooperative catalysis, enamines, multicomponent reactions",

author = "Yongming Deng and Lu Liu and Sarkisian, \{Ryan G.\} and Kraig Wheeler and Hong Wang and Zhenghu Xu",

year = "2013",

month = mar,

day = "25",

doi = "10.1002/anie.201209268",

language = "英语",

volume = "52",

pages = "3663--3667",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "13",

}

TY - JOUR

T1 - Arylamine-catalyzed enamine formation

T2 - Cooperative catalysis with arylamines and acids

AU - Deng, Yongming

AU - Liu, Lu

AU - Sarkisian, Ryan G.

AU - Wheeler, Kraig

AU - Wang, Hong

AU - Xu, Zhenghu

PY - 2013/3/25

Y1 - 2013/3/25

N2 - Powerful combination: Arylamines and metal Lewis acids are used as catalysts in the highly chemo- and enantioselective three-component inverse-electron-demand aza-Diels-Alder reaction of cyclic ketones with enones. The enantioselectivity is introduced by a simple chiral anion (see scheme). Arylamines can also serve as effective enamine catalysts in combination with either a metal Lewis acid or a Brønsted acid.

AB - Powerful combination: Arylamines and metal Lewis acids are used as catalysts in the highly chemo- and enantioselective three-component inverse-electron-demand aza-Diels-Alder reaction of cyclic ketones with enones. The enantioselectivity is introduced by a simple chiral anion (see scheme). Arylamines can also serve as effective enamine catalysts in combination with either a metal Lewis acid or a Brønsted acid.

KW - Lewis acids

KW - aza-Diels-Alder reactions

KW - cooperative catalysis

KW - enamines

KW - multicomponent reactions

UR - https://www.scopus.com/pages/publications/84875292807

U2 - 10.1002/anie.201209268

DO - 10.1002/anie.201209268

M3 - 文章

AN - SCOPUS:84875292807

SN - 1433-7851

VL - 52

SP - 3663

EP - 3667

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

Arylamine-catalyzed enamine formation: Cooperative catalysis with arylamines and acids

摘要

访问文件

其它文件与链接

指纹

引用此