TY - CHAP
T1 - Application of organic carbonates in organic transformation catalyzed by ionic liquids
AU - Wang, Binshen
AU - Elageed, Elnazeer H.M.
AU - Gao, Guohua
N1 - Publisher Copyright:
© Springer International Publishing Switzerland 2016.
PY - 2016/1/1
Y1 - 2016/1/1
N2 - Organic carbonates are renowned for their low toxicity and high biodegradability, which is considered as green reagents and an appropriate alternative to conventional toxic compounds. Additionally, organic carbonates can be produced from CO2; therefore, the transformation of organic carbonates to other valuable chemicals is an indirect way for CO2 utilization. The transformation reactions of organic carbonates mainly include alkylation reactions, carbonylation reactions, and transesterification reactions. Ionic liquids, as attractive media, have already exhibited excellent performance on promoting various transformations of organic carbonates. This chapter covers recent applications of organic carbonates in organic transformation reactions catalyzed by ionic liquids.
AB - Organic carbonates are renowned for their low toxicity and high biodegradability, which is considered as green reagents and an appropriate alternative to conventional toxic compounds. Additionally, organic carbonates can be produced from CO2; therefore, the transformation of organic carbonates to other valuable chemicals is an indirect way for CO2 utilization. The transformation reactions of organic carbonates mainly include alkylation reactions, carbonylation reactions, and transesterification reactions. Ionic liquids, as attractive media, have already exhibited excellent performance on promoting various transformations of organic carbonates. This chapter covers recent applications of organic carbonates in organic transformation reactions catalyzed by ionic liquids.
KW - Alkylation reaction
KW - Carbonylation reaction
KW - Chlorine-free reagent
KW - Ionic liquid
KW - Organic carbonate
KW - Phosgene replacement
KW - Transesterification reaction
UR - https://www.scopus.com/pages/publications/85017041860
U2 - 10.1007/978-3-319-30073-3_18
DO - 10.1007/978-3-319-30073-3_18
M3 - 章节
AN - SCOPUS:85017041860
SN - 9783319300719
SP - 483
EP - 507
BT - Chemistry Beyond Chlorine
PB - Springer International Publishing
ER -