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Anion recognition by a novel Fipronil-based receptor: efficient deprotonation or stable intermolecular hydrogen bonding

  • Chuanxiang Liu
  • , Xuhong Qian*
  • , Jiaobing Wang
  • , Zhong Li
  • *此作品的通讯作者
  • East China University of Science and Technology

科研成果: 期刊稿件文章同行评审

摘要

Strong electron-deficient heterocycles of acetyl Fipronil (F3) was designed and synthesized, its ability for anion recognition was investigated by UV and NMR analyses. This novel Fipronil-based receptor F3 shows strong binding affinity with acetate (≥107 M-1), phosphate or fluoride ion through efficient deprotonation. In addition, its interaction with chloride anion or other weak base anions through stable intermolecular H-bonding was also reported.

源语言英语
页(从-至)1087-1090
页数4
期刊Tetrahedron Letters
49
6
DOI
出版状态已出版 - 4 2月 2008
已对外发布

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