摘要
Strong electron-deficient heterocycles of acetyl Fipronil (F3) was designed and synthesized, its ability for anion recognition was investigated by UV and NMR analyses. This novel Fipronil-based receptor F3 shows strong binding affinity with acetate (≥107 M-1), phosphate or fluoride ion through efficient deprotonation. In addition, its interaction with chloride anion or other weak base anions through stable intermolecular H-bonding was also reported.
| 源语言 | 英语 |
|---|---|
| 页(从-至) | 1087-1090 |
| 页数 | 4 |
| 期刊 | Tetrahedron Letters |
| 卷 | 49 |
| 期 | 6 |
| DOI | |
| 出版状态 | 已出版 - 4 2月 2008 |
| 已对外发布 | 是 |
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