An ionic compound containing Ru(III)-complex cation and phosphotungstate anion as the efficient and recyclable catalyst for clean aerobic oxidation of alcohols

Sa Sa Wang; Jing Zhang; Cheng Liang Zhou; Giang Vo-Thanh; Ye Liu

doi:10.1016/j.catcom.2012.08.025

An ionic compound containing Ru(III)-complex cation and phosphotungstate anion as the efficient and recyclable catalyst for clean aerobic oxidation of alcohols

Sa Sa Wang
, Jing Zhang
, Cheng Liang Zhou
, Giang Vo-Thanh^*
, Ye Liu

^*此作品的通讯作者

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

19 引用（Scopus）

摘要

A novel ionic compound (3, [RuCl ₄(L) ₂] ₃PW ₁₂O ₄₀) containing the Ru(III)-complex cation and α-Keggin-type phosphotungstate anion was synthesized and proven to be the efficient catalyst for aerobic oxidations of alcohols free of base and nitroxyl radical. Specially, 3 could be reused at least five runs without obvious activity loss. The stability of 3 was dramatically improved due to the incorporation of [PW ₁₂O ₄₀] ^{3 -} as the counter-anions, leading to its available recyclability.

源语言	英语
页（从-至）	152-154
页数	3
期刊	Catalysis Communications
卷	28
DOI	https://doi.org/10.1016/j.catcom.2012.08.025
出版状态	已出版 - 5 11月 2012

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@article{a80a7a06d2d94d4594716e0bf7996a52,

title = "An ionic compound containing Ru(III)-complex cation and phosphotungstate anion as the efficient and recyclable catalyst for clean aerobic oxidation of alcohols",

abstract = "A novel ionic compound (3, [RuCl 4(L) 2] 3PW 12O 40) containing the Ru(III)-complex cation and α-Keggin-type phosphotungstate anion was synthesized and proven to be the efficient catalyst for aerobic oxidations of alcohols free of base and nitroxyl radical. Specially, 3 could be reused at least five runs without obvious activity loss. The stability of 3 was dramatically improved due to the incorporation of [PW 12O 40] 3 - as the counter-anions, leading to its available recyclability.",

keywords = "Aerobic oxidation, Homogenous catalysis, Polyoxometalates, Ruthenium complexes",

author = "Wang, \{Sa Sa\} and Jing Zhang and Zhou, \{Cheng Liang\} and Giang Vo-Thanh and Ye Liu",

year = "2012",

month = nov,

day = "5",

doi = "10.1016/j.catcom.2012.08.025",

language = "英语",

volume = "28",

pages = "152--154",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - An ionic compound containing Ru(III)-complex cation and phosphotungstate anion as the efficient and recyclable catalyst for clean aerobic oxidation of alcohols

AU - Wang, Sa Sa

AU - Zhang, Jing

AU - Zhou, Cheng Liang

AU - Vo-Thanh, Giang

AU - Liu, Ye

PY - 2012/11/5

Y1 - 2012/11/5

N2 - A novel ionic compound (3, [RuCl 4(L) 2] 3PW 12O 40) containing the Ru(III)-complex cation and α-Keggin-type phosphotungstate anion was synthesized and proven to be the efficient catalyst for aerobic oxidations of alcohols free of base and nitroxyl radical. Specially, 3 could be reused at least five runs without obvious activity loss. The stability of 3 was dramatically improved due to the incorporation of [PW 12O 40] 3 - as the counter-anions, leading to its available recyclability.

AB - A novel ionic compound (3, [RuCl 4(L) 2] 3PW 12O 40) containing the Ru(III)-complex cation and α-Keggin-type phosphotungstate anion was synthesized and proven to be the efficient catalyst for aerobic oxidations of alcohols free of base and nitroxyl radical. Specially, 3 could be reused at least five runs without obvious activity loss. The stability of 3 was dramatically improved due to the incorporation of [PW 12O 40] 3 - as the counter-anions, leading to its available recyclability.

KW - Aerobic oxidation

KW - Homogenous catalysis

KW - Polyoxometalates

KW - Ruthenium complexes

UR - https://www.scopus.com/pages/publications/84866488894

U2 - 10.1016/j.catcom.2012.08.025

DO - 10.1016/j.catcom.2012.08.025

M3 - 文章

AN - SCOPUS:84866488894

SN - 1566-7367

VL - 28

SP - 152

EP - 154

JO - Catalysis Communications

JF - Catalysis Communications

ER -

An ionic compound containing Ru(III)-complex cation and phosphotungstate anion as the efficient and recyclable catalyst for clean aerobic oxidation of alcohols

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