Amino- and sulfo-bifunctionalized metal-organic frameworks: One-pot tandem catalysis and the catalytic sites

Hui Liu; Fu Gui Xi; Wei Sun; Ning Ning Yang; En Qing Gao

doi:10.1021/acs.inorgchem.6b01057

Amino- and sulfo-bifunctionalized metal-organic frameworks: One-pot tandem catalysis and the catalytic sites

Hui Liu
, Fu Gui Xi
, Wei Sun
, Ning Ning Yang
, En Qing Gao^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

97 引用（Scopus）

摘要

New MIL-101 metal-organic frameworks (MOFs) dually functionalized with amino and sulfo groups were fabricated by postsynthetic modification and used to catalyze one-pot deacetalization-Knoevenagel condensation. We proved that the MOFs take the zwitterionic form, with the catalytic acid site being the ammonium group rather than the sulfo one. The acid and base concentrations in the materials are correlated, and the ratio can be readily tuned to achieve optimal catalytic performance.

源语言	英语
页（从-至）	5753-5755
页数	3
期刊	Inorganic Chemistry
卷	55
期	12
DOI	https://doi.org/10.1021/acs.inorgchem.6b01057
出版状态	已出版 - 20 6月 2016

访问文件

10.1021/acs.inorgchem.6b01057

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{1c52936143c84827a279e57e5505f0ed,

title = "Amino- and sulfo-bifunctionalized metal-organic frameworks: One-pot tandem catalysis and the catalytic sites",

abstract = "New MIL-101 metal-organic frameworks (MOFs) dually functionalized with amino and sulfo groups were fabricated by postsynthetic modification and used to catalyze one-pot deacetalization-Knoevenagel condensation. We proved that the MOFs take the zwitterionic form, with the catalytic acid site being the ammonium group rather than the sulfo one. The acid and base concentrations in the materials are correlated, and the ratio can be readily tuned to achieve optimal catalytic performance.",

author = "Hui Liu and Xi, \{Fu Gui\} and Wei Sun and Yang, \{Ning Ning\} and Gao, \{En Qing\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = jun,

day = "20",

doi = "10.1021/acs.inorgchem.6b01057",

language = "英语",

volume = "55",

pages = "5753--5755",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Amino- and sulfo-bifunctionalized metal-organic frameworks

T2 - One-pot tandem catalysis and the catalytic sites

AU - Liu, Hui

AU - Xi, Fu Gui

AU - Sun, Wei

AU - Yang, Ning Ning

AU - Gao, En Qing

PY - 2016/6/20

Y1 - 2016/6/20

N2 - New MIL-101 metal-organic frameworks (MOFs) dually functionalized with amino and sulfo groups were fabricated by postsynthetic modification and used to catalyze one-pot deacetalization-Knoevenagel condensation. We proved that the MOFs take the zwitterionic form, with the catalytic acid site being the ammonium group rather than the sulfo one. The acid and base concentrations in the materials are correlated, and the ratio can be readily tuned to achieve optimal catalytic performance.

AB - New MIL-101 metal-organic frameworks (MOFs) dually functionalized with amino and sulfo groups were fabricated by postsynthetic modification and used to catalyze one-pot deacetalization-Knoevenagel condensation. We proved that the MOFs take the zwitterionic form, with the catalytic acid site being the ammonium group rather than the sulfo one. The acid and base concentrations in the materials are correlated, and the ratio can be readily tuned to achieve optimal catalytic performance.

UR - https://www.scopus.com/pages/publications/84975461408

U2 - 10.1021/acs.inorgchem.6b01057

DO - 10.1021/acs.inorgchem.6b01057

M3 - 文章

AN - SCOPUS:84975461408

SN - 0020-1669

VL - 55

SP - 5753

EP - 5755

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Amino- and sulfo-bifunctionalized metal-organic frameworks: One-pot tandem catalysis and the catalytic sites

摘要

访问文件

其它文件与链接

学术指纹

引用此