Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

Huanrong Li; Bingtao Guan; Wenjin Wang; Dong Xing; Zhao Fang; Xiaobing Wan; Liping Yang; Zhangjie Shi

doi:10.1016/j.tet.2007.05.117

Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

Huanrong Li
, Bingtao Guan
, Wenjin Wang
, Dong Xing
, Zhao Fang
, Xiaobing Wan
, Liping Yang
, Zhangjie Shi^*

^*此作品的通讯作者

化学与分子工程学院

Peking University
East China Normal University
Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

48 引用（Scopus）

摘要

The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.

源语言	英语
页（从-至）	8430-8434
页数	5
期刊	Tetrahedron
卷	63
期	35
DOI	https://doi.org/10.1016/j.tet.2007.05.117
出版状态	已出版 - 27 8月 2007

访问文件

10.1016/j.tet.2007.05.117

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{73b77ce1bb184e8a80f627ddf2d5ff2f,

title = "Aerobic oxidation of alcohol in aqueous solution catalyzed by gold",

abstract = "The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.",

author = "Huanrong Li and Bingtao Guan and Wenjin Wang and Dong Xing and Zhao Fang and Xiaobing Wan and Liping Yang and Zhangjie Shi",

year = "2007",

month = aug,

day = "27",

doi = "10.1016/j.tet.2007.05.117",

language = "英语",

volume = "63",

pages = "8430--8434",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Ltd",

number = "35",

}

TY - JOUR

T1 - Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

AU - Li, Huanrong

AU - Guan, Bingtao

AU - Wang, Wenjin

AU - Xing, Dong

AU - Fang, Zhao

AU - Wan, Xiaobing

AU - Yang, Liping

AU - Shi, Zhangjie

PY - 2007/8/27

Y1 - 2007/8/27

N2 - The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.

AB - The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.

UR - https://www.scopus.com/pages/publications/34447530637

U2 - 10.1016/j.tet.2007.05.117

DO - 10.1016/j.tet.2007.05.117

M3 - 文章

AN - SCOPUS:34447530637

SN - 0040-4020

VL - 63

SP - 8430

EP - 8434

JO - Tetrahedron

JF - Tetrahedron

IS - 35

ER -

Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

摘要

访问文件

其它文件与链接

指纹

引用此