TY - JOUR
T1 - A very simple route to benzonaphtho[1,5]diazocines using vilsmeier reagents via the 't-amino effect'
AU - Cheng, Ying
AU - Yang, Hai Bo
AU - Liu, Bo
AU - Meth-Cohn, Otto
AU - Watkin, David
AU - Humphries, Stephen
PY - 2002
Y1 - 2002
N2 - The novel fused heterocyclic systems 7,8,13,14-tetrahydrobenzo[b]naphtho[1,2-f][1,5]diazocine and 7,8,13,14-tetrahydrobenzo[b]naphtho[2,1-f][1,5]diazocine were prepared in moderate yields in a one step reaction by Vilsmeier formylation of 1-dimethyl-aminonaphthalene or 2-dimethylaminonaphthalene, respectively, by way of the 't-amino effect'. Novel rearranged by-products were formed from 2-dimethylaminonaphthalene.
AB - The novel fused heterocyclic systems 7,8,13,14-tetrahydrobenzo[b]naphtho[1,2-f][1,5]diazocine and 7,8,13,14-tetrahydrobenzo[b]naphtho[2,1-f][1,5]diazocine were prepared in moderate yields in a one step reaction by Vilsmeier formylation of 1-dimethyl-aminonaphthalene or 2-dimethylaminonaphthalene, respectively, by way of the 't-amino effect'. Novel rearranged by-products were formed from 2-dimethylaminonaphthalene.
KW - Benzonaphthodiazocines
KW - Dimethylaminonaphthalenes
KW - Vilsmeier
UR - https://www.scopus.com/pages/publications/0036351244
U2 - 10.1055/s-2002-28513
DO - 10.1055/s-2002-28513
M3 - 文章
AN - SCOPUS:0036351244
SN - 0039-7881
SP - 906
EP - 910
JO - Synthesis (Germany)
JF - Synthesis (Germany)
IS - 7
ER -