A switchable ferrocene-based [1]rotaxane with an electrochemical signal output

Hong Li; Hui Zhang; Qiong Zhang; Qi Wei Zhang; Da Hui Qu

doi:10.1021/ol302826g

A switchable ferrocene-based [1]rotaxane with an electrochemical signal output

Hong Li
, Hui Zhang
, Qiong Zhang
, Qi Wei Zhang
, Da Hui Qu^*

^*此作品的通讯作者

East China University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

56 引用（Scopus）

摘要

A [1]rotaxane, in which a linear rod is attached to one cyclopentadienyl (Cp) ring of a ferrocene unit and threaded into a dibenzo-24-crown-8 connected to the other Cp ring, was prepared. The mechanical motion of the rod-like part relative to the macrocycle has been demonstrated using ¹H NMR spectroscopy. Cyclic voltammetry (CV) showed that the system can be chemically switched between electrochemically reversible and irreversible states, depending on the inclusion and exclusion of the ammonium/amine group from the macrocycle.

源语言	英语
页（从-至）	5900-5903
页数	4
期刊	Organic Letters
卷	14
期	23
DOI	https://doi.org/10.1021/ol302826g
出版状态	已出版 - 7 12月 2012
已对外发布	是

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abstract = "A [1]rotaxane, in which a linear rod is attached to one cyclopentadienyl (Cp) ring of a ferrocene unit and threaded into a dibenzo-24-crown-8 connected to the other Cp ring, was prepared. The mechanical motion of the rod-like part relative to the macrocycle has been demonstrated using 1H NMR spectroscopy. Cyclic voltammetry (CV) showed that the system can be chemically switched between electrochemically reversible and irreversible states, depending on the inclusion and exclusion of the ammonium/amine group from the macrocycle.",

author = "Hong Li and Hui Zhang and Qiong Zhang and Zhang, \{Qi Wei\} and Qu, \{Da Hui\}",

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T1 - A switchable ferrocene-based [1]rotaxane with an electrochemical signal output

AU - Li, Hong

AU - Zhang, Hui

AU - Zhang, Qiong

AU - Zhang, Qi Wei

AU - Qu, Da Hui

PY - 2012/12/7

Y1 - 2012/12/7

N2 - A [1]rotaxane, in which a linear rod is attached to one cyclopentadienyl (Cp) ring of a ferrocene unit and threaded into a dibenzo-24-crown-8 connected to the other Cp ring, was prepared. The mechanical motion of the rod-like part relative to the macrocycle has been demonstrated using 1H NMR spectroscopy. Cyclic voltammetry (CV) showed that the system can be chemically switched between electrochemically reversible and irreversible states, depending on the inclusion and exclusion of the ammonium/amine group from the macrocycle.

AB - A [1]rotaxane, in which a linear rod is attached to one cyclopentadienyl (Cp) ring of a ferrocene unit and threaded into a dibenzo-24-crown-8 connected to the other Cp ring, was prepared. The mechanical motion of the rod-like part relative to the macrocycle has been demonstrated using 1H NMR spectroscopy. Cyclic voltammetry (CV) showed that the system can be chemically switched between electrochemically reversible and irreversible states, depending on the inclusion and exclusion of the ammonium/amine group from the macrocycle.

UR - https://www.scopus.com/pages/publications/84870873522

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DO - 10.1021/ol302826g

M3 - 文章

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SN - 1523-7060

VL - 14

SP - 5900

EP - 5903

JO - Organic Letters

JF - Organic Letters

IS - 23

ER -

A switchable ferrocene-based [1]rotaxane with an electrochemical signal output

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