A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles

Jiafeng He; Xun Shen Liu; Mingjia Li; Shaoting Peng; Zhi Yao Si; Lu Liu

doi:10.1039/d3qo00125c

A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles

Jiafeng He
, Xun Shen Liu
, Mingjia Li
, Shaoting Peng
, Zhi Yao Si
, Lu Liu^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

9 引用（Scopus）

摘要

A Rh(ii)-catalyzed highly stereoselective chalcogenide ylide formation/Smiles rearrangement reaction of diaryl thioether/selenoethers and triazoles was successfully developed, which provided an efficient strategy to construct trisubstituted acyclic vinyl sulfides/selenides. The salient features of this protocol include simple operation, readily available starting materials, atom economy, broad substrate scope, and convenient transformation of products.

源语言	英语
页（从-至）	2198-2203
页数	6
期刊	Organic Chemistry Frontiers
卷	10
期	9
DOI	https://doi.org/10.1039/d3qo00125c
出版状态	已出版 - 24 3月 2023

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10.1039/d3qo00125c

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abstract = "A Rh(ii)-catalyzed highly stereoselective chalcogenide ylide formation/Smiles rearrangement reaction of diaryl thioether/selenoethers and triazoles was successfully developed, which provided an efficient strategy to construct trisubstituted acyclic vinyl sulfides/selenides. The salient features of this protocol include simple operation, readily available starting materials, atom economy, broad substrate scope, and convenient transformation of products.",

author = "Jiafeng He and Liu, \{Xun Shen\} and Mingjia Li and Shaoting Peng and Si, \{Zhi Yao\} and Lu Liu",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

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doi = "10.1039/d3qo00125c",

language = "英语",

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T1 - A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles

AU - He, Jiafeng

AU - Liu, Xun Shen

AU - Li, Mingjia

AU - Peng, Shaoting

AU - Si, Zhi Yao

AU - Liu, Lu

PY - 2023/3/24

Y1 - 2023/3/24

N2 - A Rh(ii)-catalyzed highly stereoselective chalcogenide ylide formation/Smiles rearrangement reaction of diaryl thioether/selenoethers and triazoles was successfully developed, which provided an efficient strategy to construct trisubstituted acyclic vinyl sulfides/selenides. The salient features of this protocol include simple operation, readily available starting materials, atom economy, broad substrate scope, and convenient transformation of products.

AB - A Rh(ii)-catalyzed highly stereoselective chalcogenide ylide formation/Smiles rearrangement reaction of diaryl thioether/selenoethers and triazoles was successfully developed, which provided an efficient strategy to construct trisubstituted acyclic vinyl sulfides/selenides. The salient features of this protocol include simple operation, readily available starting materials, atom economy, broad substrate scope, and convenient transformation of products.

UR - https://www.scopus.com/pages/publications/85151811519

U2 - 10.1039/d3qo00125c

DO - 10.1039/d3qo00125c

M3 - 文章

AN - SCOPUS:85151811519

SN - 2052-4110

VL - 10

SP - 2198

EP - 2203

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 9

ER -

A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles

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