A practical synthesis of novel chiral sulfoxide-nitrogen ligands

Ming Wang; Jianpeng Wei; Qiaoling Fan; Xuefeng Jiang

doi:10.1016/j.tet.2015.08.004

A practical synthesis of novel chiral sulfoxide-nitrogen ligands

Ming Wang
, Jianpeng Wei
, Qiaoling Fan
, Xuefeng Jiang^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University
Nankai University

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

Novel chiral sulfoxide-nitrogen ligands which are derived from amino alcohols were developed. All of fourteen sulfoxide-nitrogen ligands can be synthesized by three steps without any chiral auxiliary. In addition, every step of the synthesis can be achieved in gram-scale by using the preparation of L9-L12 as examples. These sulfoxide-nitrogen ligands may be applicable to the asymmetric catalytic 1,3-dipolar cycloaddition of azomethine ylide with alkylidene malonate.

源语言	英语
页（从-至）	2671-2676
页数	6
期刊	Tetrahedron
卷	72
期	21
DOI	https://doi.org/10.1016/j.tet.2015.08.004
出版状态	已出版 - 26 5月 2016

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10.1016/j.tet.2015.08.004

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title = "A practical synthesis of novel chiral sulfoxide-nitrogen ligands",

abstract = "Novel chiral sulfoxide-nitrogen ligands which are derived from amino alcohols were developed. All of fourteen sulfoxide-nitrogen ligands can be synthesized by three steps without any chiral auxiliary. In addition, every step of the synthesis can be achieved in gram-scale by using the preparation of L9-L12 as examples. These sulfoxide-nitrogen ligands may be applicable to the asymmetric catalytic 1,3-dipolar cycloaddition of azomethine ylide with alkylidene malonate.",

keywords = "Chiral ligands, Gram-scale preparation, Oxidation, Sulfoxide",

author = "Ming Wang and Jianpeng Wei and Qiaoling Fan and Xuefeng Jiang",

year = "2016",

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day = "26",

doi = "10.1016/j.tet.2015.08.004",

language = "英语",

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T1 - A practical synthesis of novel chiral sulfoxide-nitrogen ligands

AU - Wang, Ming

AU - Wei, Jianpeng

AU - Fan, Qiaoling

AU - Jiang, Xuefeng

PY - 2016/5/26

Y1 - 2016/5/26

N2 - Novel chiral sulfoxide-nitrogen ligands which are derived from amino alcohols were developed. All of fourteen sulfoxide-nitrogen ligands can be synthesized by three steps without any chiral auxiliary. In addition, every step of the synthesis can be achieved in gram-scale by using the preparation of L9-L12 as examples. These sulfoxide-nitrogen ligands may be applicable to the asymmetric catalytic 1,3-dipolar cycloaddition of azomethine ylide with alkylidene malonate.

AB - Novel chiral sulfoxide-nitrogen ligands which are derived from amino alcohols were developed. All of fourteen sulfoxide-nitrogen ligands can be synthesized by three steps without any chiral auxiliary. In addition, every step of the synthesis can be achieved in gram-scale by using the preparation of L9-L12 as examples. These sulfoxide-nitrogen ligands may be applicable to the asymmetric catalytic 1,3-dipolar cycloaddition of azomethine ylide with alkylidene malonate.

KW - Chiral ligands

KW - Gram-scale preparation

KW - Oxidation

KW - Sulfoxide

UR - https://www.scopus.com/pages/publications/84940061518

U2 - 10.1016/j.tet.2015.08.004

DO - 10.1016/j.tet.2015.08.004

M3 - 文章

AN - SCOPUS:84940061518

SN - 0040-4020

VL - 72

SP - 2671

EP - 2676

JO - Tetrahedron

JF - Tetrahedron

IS - 21

ER -

A practical synthesis of novel chiral sulfoxide-nitrogen ligands

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