A New Technology for the Preparation of High-permeance ZSM-5 Zeolite Membrane

Yong Sheng Li; Jin Qu Wang; Jian Lin Shi; Lian Zhang Chen; Shu Cai Guo; Dong Sheng Yan

A New Technology for the Preparation of High-permeance ZSM-5 Zeolite Membrane

Yong Sheng Li^*
, Jin Qu Wang
, Jian Lin Shi
, Lian Zhang Chen
, Shu Cai Guo
, Dong Sheng Yan

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

High-permeance ZSM-5 zeolite membrane was prepared on porous tubular α-Al₂O₃ support by varying-temperature hydrothermal synthesis. XRD patterns show that the membrane consists of ZSM-5 zeolite crystals. SEM analysis indicates that few defects exist in the membrane and the thickness of the membrane is about 9 μm. The hydrogen permeance through the membrane is about 2.4×10^-6mol/(m² · s · Pa), and the separation factor for n-C₄H₁₀/i-C₄H₁₀ mixture (volume ratio 1 : 1) is 40, which indicates that it has a high quality with high permeance and selectivity. Repeated nucleation and re-growth of the crystals on the support result in the dense membrane formation.

源语言	英语
页（从-至）	1859
页数	1
期刊	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
卷	23
期	10
出版状态	已出版 - 10月 2002
已对外发布	是

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引用此

@article{3e74409a85224b47823ed01009033453,

title = "A New Technology for the Preparation of High-permeance ZSM-5 Zeolite Membrane",

abstract = "High-permeance ZSM-5 zeolite membrane was prepared on porous tubular α-Al2O3 support by varying-temperature hydrothermal synthesis. XRD patterns show that the membrane consists of ZSM-5 zeolite crystals. SEM analysis indicates that few defects exist in the membrane and the thickness of the membrane is about 9 μm. The hydrogen permeance through the membrane is about 2.4×10-6mol/(m2 · s · Pa), and the separation factor for n-C4H10/i-C4H10 mixture (volume ratio 1 : 1) is 40, which indicates that it has a high quality with high permeance and selectivity. Repeated nucleation and re-growth of the crystals on the support result in the dense membrane formation.",

keywords = "Permeance, Separation factor, Varying-temperature synthesis, ZSM-5 zeolite membrane",

author = "Li, \{Yong Sheng\} and Wang, \{Jin Qu\} and Shi, \{Jian Lin\} and Chen, \{Lian Zhang\} and Guo, \{Shu Cai\} and Yan, \{Dong Sheng\}",

year = "2002",

month = oct,

language = "英语",

volume = "23",

pages = "1859",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "10",

}

TY - JOUR

T1 - A New Technology for the Preparation of High-permeance ZSM-5 Zeolite Membrane

AU - Li, Yong Sheng

AU - Wang, Jin Qu

AU - Shi, Jian Lin

AU - Chen, Lian Zhang

AU - Guo, Shu Cai

AU - Yan, Dong Sheng

PY - 2002/10

Y1 - 2002/10

N2 - High-permeance ZSM-5 zeolite membrane was prepared on porous tubular α-Al2O3 support by varying-temperature hydrothermal synthesis. XRD patterns show that the membrane consists of ZSM-5 zeolite crystals. SEM analysis indicates that few defects exist in the membrane and the thickness of the membrane is about 9 μm. The hydrogen permeance through the membrane is about 2.4×10-6mol/(m2 · s · Pa), and the separation factor for n-C4H10/i-C4H10 mixture (volume ratio 1 : 1) is 40, which indicates that it has a high quality with high permeance and selectivity. Repeated nucleation and re-growth of the crystals on the support result in the dense membrane formation.

AB - High-permeance ZSM-5 zeolite membrane was prepared on porous tubular α-Al2O3 support by varying-temperature hydrothermal synthesis. XRD patterns show that the membrane consists of ZSM-5 zeolite crystals. SEM analysis indicates that few defects exist in the membrane and the thickness of the membrane is about 9 μm. The hydrogen permeance through the membrane is about 2.4×10-6mol/(m2 · s · Pa), and the separation factor for n-C4H10/i-C4H10 mixture (volume ratio 1 : 1) is 40, which indicates that it has a high quality with high permeance and selectivity. Repeated nucleation and re-growth of the crystals on the support result in the dense membrane formation.

KW - Permeance

KW - Separation factor

KW - Varying-temperature synthesis

KW - ZSM-5 zeolite membrane

UR - https://www.scopus.com/pages/publications/0347899562

M3 - 文章

AN - SCOPUS:0347899562

SN - 0251-0790

VL - 23

SP - 1859

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 10

ER -