A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

Huabin Zhang; Mingjian Zhang; Ping Lin; Victor Malgras; Jing Tang; Saad M. Alshehri; Yusuke Yamauchi; Shaowu Du; Jian Zhang

doi:10.1002/chem.201503561

A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

Huabin Zhang
, Mingjian Zhang
, Ping Lin
, Victor Malgras
, Jing Tang
, Saad M. Alshehri
, Yusuke Yamauchi^*
, Shaowu Du
, Jian Zhang

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter
National Institute for Materials Science Tsukuba
Waseda University
King Saud University

科研成果: 期刊稿件 › 文章 › 同行评审

71 引用（Scopus）

摘要

Metal-organic framework (MOF)-based energetic material [Cu₃(MA)₂(N₃)₃] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73kJ mol^-1, which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.

源语言	英语
页（从-至）	1141-1145
页数	5
期刊	Chemistry - A European Journal
卷	22
期	3
DOI	https://doi.org/10.1002/chem.201503561
出版状态	已出版 - 18 1月 2016
已对外发布	是

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title = "A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material",

abstract = "Metal-organic framework (MOF)-based energetic material [Cu3(MA)2(N3)3] (1; MA=melamine) was synthesized and structurally characterized (47.55 \% N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73kJ mol-1, which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.",

keywords = "N ligands, helical structures, high-energy materials, hydrothermal synthesis, metal-organic frameworks",

author = "Huabin Zhang and Mingjian Zhang and Ping Lin and Victor Malgras and Jing Tang and Alshehri, \{Saad M.\} and Yusuke Yamauchi and Shaowu Du and Jian Zhang",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

year = "2016",

month = jan,

day = "18",

doi = "10.1002/chem.201503561",

language = "英语",

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TY - JOUR

T1 - A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

AU - Zhang, Huabin

AU - Zhang, Mingjian

AU - Lin, Ping

AU - Malgras, Victor

AU - Tang, Jing

AU - Alshehri, Saad M.

AU - Yamauchi, Yusuke

AU - Du, Shaowu

AU - Zhang, Jian

PY - 2016/1/18

Y1 - 2016/1/18

N2 - Metal-organic framework (MOF)-based energetic material [Cu3(MA)2(N3)3] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73kJ mol-1, which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.

AB - Metal-organic framework (MOF)-based energetic material [Cu3(MA)2(N3)3] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73kJ mol-1, which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.

KW - N ligands

KW - helical structures

KW - high-energy materials

KW - hydrothermal synthesis

KW - metal-organic frameworks

UR - https://www.scopus.com/pages/publications/84954026816

U2 - 10.1002/chem.201503561

DO - 10.1002/chem.201503561

M3 - 文章

AN - SCOPUS:84954026816

SN - 0947-6539

VL - 22

SP - 1141

EP - 1145

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 3

ER -

A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

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