A highly efficient friedel-crafts reaction of tertiary α- hydroxyesters or α-hydroxyketones to α-quaternary esters or ketones

Long Chen; Jian Zhou

doi:10.1002/asia.201200693

A highly efficient friedel-crafts reaction of tertiary α- hydroxyesters or α-hydroxyketones to α-quaternary esters or ketones

Long Chen
, Jian Zhou^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

40 引用（Scopus）

摘要

A catalytic Friedel-Crafts arylation of α-hydroxyesters or α-hydroxyketones with electron-rich aromatic compounds to furnish α-quaternary esters/ketones has been developed. The cheap and easy to handle catalyst HClO ₄ (70 %, aq) was identified as a powerful catalyst for this arylation reaction.

源语言	英语
页（从-至）	2510-2515
页数	6
期刊	Chemistry - An Asian Journal
卷	7
期	11
DOI	https://doi.org/10.1002/asia.201200693
出版状态	已出版 - 11月 2012

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10.1002/asia.201200693

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title = "A highly efficient friedel-crafts reaction of tertiary α- hydroxyesters or α-hydroxyketones to α-quaternary esters or ketones",

abstract = "A catalytic Friedel-Crafts arylation of α-hydroxyesters or α-hydroxyketones with electron-rich aromatic compounds to furnish α-quaternary esters/ketones has been developed. The cheap and easy to handle catalyst HClO 4 (70 \%, aq) was identified as a powerful catalyst for this arylation reaction.",

keywords = "Friedel-Crafts reaction, alcohols, heterocycles, homogeneous catalysis, ketones",

author = "Long Chen and Jian Zhou",

year = "2012",

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doi = "10.1002/asia.201200693",

language = "英语",

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AU - Zhou, Jian

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N2 - A catalytic Friedel-Crafts arylation of α-hydroxyesters or α-hydroxyketones with electron-rich aromatic compounds to furnish α-quaternary esters/ketones has been developed. The cheap and easy to handle catalyst HClO 4 (70 %, aq) was identified as a powerful catalyst for this arylation reaction.

AB - A catalytic Friedel-Crafts arylation of α-hydroxyesters or α-hydroxyketones with electron-rich aromatic compounds to furnish α-quaternary esters/ketones has been developed. The cheap and easy to handle catalyst HClO 4 (70 %, aq) was identified as a powerful catalyst for this arylation reaction.

KW - Friedel-Crafts reaction

KW - alcohols

KW - heterocycles

KW - homogeneous catalysis

KW - ketones

UR - https://www.scopus.com/pages/publications/84867459848

U2 - 10.1002/asia.201200693

DO - 10.1002/asia.201200693

M3 - 文章

AN - SCOPUS:84867459848

SN - 1861-4728

VL - 7

SP - 2510

EP - 2515

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 11

ER -

A highly efficient friedel-crafts reaction of tertiary α- hydroxyesters or α-hydroxyketones to α-quaternary esters or ketones

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