A Hg(ClO4)2 3 3H2O Catalyzed sakurai-hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane

Zhong Yan Cao; Yan Zhang; Cong Bin Ji; Jian Zhou

doi:10.1021/ol202705g

A Hg(ClO₄)₂ 3 3H₂O Catalyzed sakurai-hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane

Zhong Yan Cao^*
, Yan Zhang
, Cong Bin Ji
, Jian Zhou

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

104 引用（Scopus）

摘要

It is reported that Hg(ClO₄)₂ 3 3H₂O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol %. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.

源语言	英语
页（从-至）	6398-6401
页数	4
期刊	Organic Letters
卷	13
期	24
DOI	https://doi.org/10.1021/ol202705g
出版状态	已出版 - 16 12月 2011

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10.1021/ol202705g

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abstract = "It is reported that Hg(ClO4)2 3 3H2O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol \%. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.",

author = "Cao, \{Zhong Yan\} and Yan Zhang and Ji, \{Cong Bin\} and Jian Zhou",

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AU - Cao, Zhong Yan

AU - Zhang, Yan

AU - Ji, Cong Bin

AU - Zhou, Jian

PY - 2011/12/16

Y1 - 2011/12/16

N2 - It is reported that Hg(ClO4)2 3 3H2O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol %. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.

AB - It is reported that Hg(ClO4)2 3 3H2O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol %. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.

UR - https://www.scopus.com/pages/publications/84055200425

U2 - 10.1021/ol202705g

DO - 10.1021/ol202705g

M3 - 文章

AN - SCOPUS:84055200425

SN - 1523-7060

VL - 13

SP - 6398

EP - 6401

JO - Organic Letters

JF - Organic Letters

IS - 24

ER -

A Hg(ClO4)2 3 3H2O Catalyzed sakurai-hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane

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A Hg(ClO₄)₂ 3 3H₂O Catalyzed sakurai-hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane