A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon

Grace E. Ferris; Kai Hong; Ian A. Roundtree; James P. Morken

doi:10.1021/ja400506j

A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon

Grace E. Ferris
, Kai Hong
, Ian A. Roundtree
, James P. Morken^*

^*此作品的通讯作者

Boston College

科研成果: 期刊稿件 › 文章 › 同行评审

79 引用（Scopus）

摘要

Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.

源语言	英语
页（从-至）	2501-2504
页数	4
期刊	Journal of the American Chemical Society
卷	135
期	7
DOI	https://doi.org/10.1021/ja400506j
出版状态	已出版 - 20 2月 2013
已对外发布	是

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abstract = "Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.",

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AU - Roundtree, Ian A.

AU - Morken, James P.

PY - 2013/2/20

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N2 - Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.

AB - Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.

UR - https://www.scopus.com/pages/publications/84874102435

U2 - 10.1021/ja400506j

DO - 10.1021/ja400506j

M3 - 文章

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AN - SCOPUS:84874102435

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A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon

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