环境 pH 条件下 Fe^{2 +} 活化过二硫酸盐降解有机污染物的效能与影响因素

Peroxydisulfate (PDS) activation by Fe^{2 +} has proven to be a promising method to abate emerging organic contaminants by generating reactive oxidation species. Nevertheless, this process may only achieve good decontamination performance under acidic conditions, which has markedly limited its application in real practice. To address this issue, we comprehensively investigated the performance of the Fe^{2 +} / PDS process toward some probe contaminants at different pH levels and explored the potential change in reactive oxidative species and the influence of oxygen. Both SO₄^-. and Fe(IV) were identified to be involved in the Fe^{2 +} / PDS process, and the types of these oxidative species did not change with varying pH values. Although dissolved oxygen could compete with PDS for Fe^{2 +} , especially at high pH values, this competition process was not the major reason for the declined performance of the Fe^{2 +} / PDS process, since 37. 6%- 100% of PDS could also be activated with the presence of oxygen. Instead, the overdosing of Fe^{2 +} could greatly inhibit carbamazepine removal, indicating that the nonproductive consumption of reactive oxidants by Fe^{2 +} should account for the declined performance of Fe^{2 +} / PDS under environmentally relevant pH conditions. Accordingly, the feasibility of applying zero-valent iron and sulfidated zero-valent iron was further evaluated, and the formation of corrosion products was characterized using X-ray absorption fine structure spectroscopy. All these findings will improve our understanding about the Fe^{2 +} / PDS process and thus facilitate its application.