Zn–Porphyrin-Functionalized Hollow Microporous Organic Nanospheres and Their Application for the Oxidative Coupling of Thiols

Shengguang Gao; Li Zhang; Haitao Yu; Huaqing Wang; Zhiwei He; Chunmei Song; Kun Huang

doi:10.1002/macp.202000375

Zn–Porphyrin-Functionalized Hollow Microporous Organic Nanospheres and Their Application for the Oxidative Coupling of Thiols

Shengguang Gao
, Li Zhang
, Haitao Yu
, Huaqing Wang
, Zhiwei He
, Chunmei Song^*
, Kun Huang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Novel meso-tetraphenylporphyrin zinc(II) (ZnTPP)-functionalized hollow microporous organic nanospheres (ZnTPP@HMONs) are successfully prepared a via hyper-crosslinking-induced self-assembly strategy and following postcomplexation with zinc(II) ions using polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and meso-tetraphenylporphyrin (H₂TPP) as precursors. The obtained ZnTPP@HMONs possess a micro/mesoporous structure, high special surface area, and robust organic framework. In particular, the inner hollow cavity in ZnTPP@HMONs catalyst can be beneficial to the diffusion of substrates and products. Therefore, the prepared ZnTPP@HMONs exhibit excellent catalytic performance and good reusability in the oxidative coupling of thiols.

Original language	English
Article number	2000375
Journal	Macromolecular Chemistry and Physics
Volume	222
Issue number	3
DOIs	https://doi.org/10.1002/macp.202000375
State	Published - Feb 2021

Keywords

Zn–porphyrin
hollow microporous organic nanospheres
hyper-crosslinking-induced self-assembly
oxidative coupling of thiols

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10.1002/macp.202000375

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@article{ed2abdf65fa14054b400717b864f0cf8,

title = "Zn–Porphyrin-Functionalized Hollow Microporous Organic Nanospheres and Their Application for the Oxidative Coupling of Thiols",

abstract = "Novel meso-tetraphenylporphyrin zinc(II) (ZnTPP)-functionalized hollow microporous organic nanospheres (ZnTPP@HMONs) are successfully prepared a via hyper-crosslinking-induced self-assembly strategy and following postcomplexation with zinc(II) ions using polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and meso-tetraphenylporphyrin (H2TPP) as precursors. The obtained ZnTPP@HMONs possess a micro/mesoporous structure, high special surface area, and robust organic framework. In particular, the inner hollow cavity in ZnTPP@HMONs catalyst can be beneficial to the diffusion of substrates and products. Therefore, the prepared ZnTPP@HMONs exhibit excellent catalytic performance and good reusability in the oxidative coupling of thiols.",

keywords = "Zn–porphyrin, hollow microporous organic nanospheres, hyper-crosslinking-induced self-assembly, oxidative coupling of thiols",

author = "Shengguang Gao and Li Zhang and Haitao Yu and Huaqing Wang and Zhiwei He and Chunmei Song and Kun Huang",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH GmbH",

year = "2021",

month = feb,

doi = "10.1002/macp.202000375",

language = "英语",

volume = "222",

journal = "Macromolecular Chemistry and Physics",

issn = "1022-1352",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Zn–Porphyrin-Functionalized Hollow Microporous Organic Nanospheres and Their Application for the Oxidative Coupling of Thiols

AU - Gao, Shengguang

AU - Zhang, Li

AU - Yu, Haitao

AU - Wang, Huaqing

AU - He, Zhiwei

AU - Song, Chunmei

AU - Huang, Kun

PY - 2021/2

Y1 - 2021/2

N2 - Novel meso-tetraphenylporphyrin zinc(II) (ZnTPP)-functionalized hollow microporous organic nanospheres (ZnTPP@HMONs) are successfully prepared a via hyper-crosslinking-induced self-assembly strategy and following postcomplexation with zinc(II) ions using polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and meso-tetraphenylporphyrin (H2TPP) as precursors. The obtained ZnTPP@HMONs possess a micro/mesoporous structure, high special surface area, and robust organic framework. In particular, the inner hollow cavity in ZnTPP@HMONs catalyst can be beneficial to the diffusion of substrates and products. Therefore, the prepared ZnTPP@HMONs exhibit excellent catalytic performance and good reusability in the oxidative coupling of thiols.

AB - Novel meso-tetraphenylporphyrin zinc(II) (ZnTPP)-functionalized hollow microporous organic nanospheres (ZnTPP@HMONs) are successfully prepared a via hyper-crosslinking-induced self-assembly strategy and following postcomplexation with zinc(II) ions using polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and meso-tetraphenylporphyrin (H2TPP) as precursors. The obtained ZnTPP@HMONs possess a micro/mesoporous structure, high special surface area, and robust organic framework. In particular, the inner hollow cavity in ZnTPP@HMONs catalyst can be beneficial to the diffusion of substrates and products. Therefore, the prepared ZnTPP@HMONs exhibit excellent catalytic performance and good reusability in the oxidative coupling of thiols.

KW - Zn–porphyrin

KW - hollow microporous organic nanospheres

KW - hyper-crosslinking-induced self-assembly

KW - oxidative coupling of thiols

UR - https://www.scopus.com/pages/publications/85098115269

U2 - 10.1002/macp.202000375

DO - 10.1002/macp.202000375

M3 - 文章

AN - SCOPUS:85098115269

SN - 1022-1352

VL - 222

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 3

M1 - 2000375

ER -

Zn–Porphyrin-Functionalized Hollow Microporous Organic Nanospheres and Their Application for the Oxidative Coupling of Thiols

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Keywords

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