Visible-Light-Mediated C(sp3)–H Thiocarbonylation for Thiolactam Preparation with Potassium Sulfide

Wei Tan; Cuihong Wang; Xuefeng Jiang

doi:10.1002/cjoc.201900360

Visible-Light-Mediated C(sp³)–H Thiocarbonylation for Thiolactam Preparation with Potassium Sulfide

Wei Tan
, Cuihong Wang
, Xuefeng Jiang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

We report herein a protocol for thiolactam preparation with potassium sulfide via visible-light-mediated C(sp³)–H thiocarbonylation, in which polysulfide dianions and radical anions generated from potassium sulfide were the key active species. A variety of thiolactams were straightforward established under mild conditions. Moreover, it was successfully applied to structural modification of tetrahydroberberine.

Original language	English
Pages (from-to)	1234-1238
Number of pages	5
Journal	Chinese Journal of Chemistry
Volume	37
Issue number	12
DOIs	https://doi.org/10.1002/cjoc.201900360
State	Published - 1 Dec 2019

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title = "Visible-Light-Mediated C(sp3)–H Thiocarbonylation for Thiolactam Preparation with Potassium Sulfide",

abstract = "We report herein a protocol for thiolactam preparation with potassium sulfide via visible-light-mediated C(sp3)–H thiocarbonylation, in which polysulfide dianions and radical anions generated from potassium sulfide were the key active species. A variety of thiolactams were straightforward established under mild conditions. Moreover, it was successfully applied to structural modification of tetrahydroberberine.",

author = "Wei Tan and Cuihong Wang and Xuefeng Jiang",

note = "Publisher Copyright: {\textcopyright} 2019 SIOC, CAS, Shanghai, \& WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

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AU - Tan, Wei

AU - Wang, Cuihong

AU - Jiang, Xuefeng

PY - 2019/12/1

Y1 - 2019/12/1

N2 - We report herein a protocol for thiolactam preparation with potassium sulfide via visible-light-mediated C(sp3)–H thiocarbonylation, in which polysulfide dianions and radical anions generated from potassium sulfide were the key active species. A variety of thiolactams were straightforward established under mild conditions. Moreover, it was successfully applied to structural modification of tetrahydroberberine.

AB - We report herein a protocol for thiolactam preparation with potassium sulfide via visible-light-mediated C(sp3)–H thiocarbonylation, in which polysulfide dianions and radical anions generated from potassium sulfide were the key active species. A variety of thiolactams were straightforward established under mild conditions. Moreover, it was successfully applied to structural modification of tetrahydroberberine.

UR - https://www.scopus.com/pages/publications/85075129159

U2 - 10.1002/cjoc.201900360

DO - 10.1002/cjoc.201900360

M3 - 文章

AN - SCOPUS:85075129159

SN - 1001-604X

VL - 37

SP - 1234

EP - 1238

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 12

ER -

Visible-Light-Mediated C(sp³)–H Thiocarbonylation for Thiolactam Preparation with Potassium Sulfide

Abstract

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