Upgrading pyrolysis oil over Ni/HZSM-5 by cascade reactions

Chen Zhao; Johannes A. Lercher

doi:10.1002/anie.201108306

Upgrading pyrolysis oil over Ni/HZSM-5 by cascade reactions

Chen Zhao^*, Johannes A. Lercher

^*Corresponding author for this work

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

321 Scopus citations

Abstract

Bio-oil to hydrocarbon oil: An active, selective, and stable catalyst (Ni supported in zeolite HZSM-5) allows the conversion of a wide variety of C-O and C-O bonds in n-hexane-extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatization reactions. Quantitative yields of C ₅-C ₉ gasoline-range hydrocarbons are obtained under mild conditions in water.

Original language	English
Pages (from-to)	5935-5940
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	24
DOIs	https://doi.org/10.1002/anie.201108306
State	Published - 11 Jun 2012
Externally published	Yes

Keywords

bio-oil
hydrocarbons
hydrodeoxygenation
hydrogenolysis
phenolic compounds

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abstract = "Bio-oil to hydrocarbon oil: An active, selective, and stable catalyst (Ni supported in zeolite HZSM-5) allows the conversion of a wide variety of C-O and C-O bonds in n-hexane-extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatization reactions. Quantitative yields of C 5-C 9 gasoline-range hydrocarbons are obtained under mild conditions in water.",

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author = "Chen Zhao and Lercher, \{Johannes A.\}",

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AU - Lercher, Johannes A.

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N2 - Bio-oil to hydrocarbon oil: An active, selective, and stable catalyst (Ni supported in zeolite HZSM-5) allows the conversion of a wide variety of C-O and C-O bonds in n-hexane-extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatization reactions. Quantitative yields of C 5-C 9 gasoline-range hydrocarbons are obtained under mild conditions in water.

AB - Bio-oil to hydrocarbon oil: An active, selective, and stable catalyst (Ni supported in zeolite HZSM-5) allows the conversion of a wide variety of C-O and C-O bonds in n-hexane-extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatization reactions. Quantitative yields of C 5-C 9 gasoline-range hydrocarbons are obtained under mild conditions in water.

KW - bio-oil

KW - hydrocarbons

KW - hydrodeoxygenation

KW - hydrogenolysis

KW - phenolic compounds

UR - https://www.scopus.com/pages/publications/84858079094

U2 - 10.1002/anie.201108306

DO - 10.1002/anie.201108306

M3 - 文章

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AN - SCOPUS:84858079094

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 24

ER -

Upgrading pyrolysis oil over Ni/HZSM-5 by cascade reactions

Abstract

Keywords

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