Unexpected self-assembly of chiral triangles from 90 chiral Di-Pt(II) acceptors

Jiang Kun Ou-Yang; Yan Yan Zhang; Meng Lan He; Jiang Tao Li; Xiaopeng Li; Xiao Li Zhao; Cui Hong Wang; Yihua Yu; De Xian Wang; Lin Xu; Hai Bo Yang

doi:10.1021/ol4032649

Unexpected self-assembly of chiral triangles from 90 chiral Di-Pt(II) acceptors

Jiang Kun Ou-Yang
, Yan Yan Zhang
, Meng Lan He
, Jiang Tao Li
, Xiaopeng Li^*
, Xiao Li Zhao
, Cui Hong Wang
, Yihua Yu
, De Xian Wang
, Lin Xu
, Hai Bo Yang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Two unexpected chiral organometallic triangles rather than squares from newly designed 90 chiral di-Pt(II) acceptors were obtained through coordination-driven self-assembly. Their structures were well characterized by multinuclear NMR (¹H and ³¹P) and variable-temperature NMR experiments, ESI-TOF-MS, and elemental analysis. The PM6 semiempirical molecular simulation was employed for the interpretation of the formation and stability of such chiral triangles.

Original language	English
Pages (from-to)	664-667
Number of pages	4
Journal	Organic Letters
Volume	16
Issue number	3
DOIs	https://doi.org/10.1021/ol4032649
State	Published - 7 Feb 2014

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title = "Unexpected self-assembly of chiral triangles from 90 chiral Di-Pt(II) acceptors",

abstract = "Two unexpected chiral organometallic triangles rather than squares from newly designed 90 chiral di-Pt(II) acceptors were obtained through coordination-driven self-assembly. Their structures were well characterized by multinuclear NMR (1H and 31P) and variable-temperature NMR experiments, ESI-TOF-MS, and elemental analysis. The PM6 semiempirical molecular simulation was employed for the interpretation of the formation and stability of such chiral triangles.",

author = "Ou-Yang, \{Jiang Kun\} and Zhang, \{Yan Yan\} and He, \{Meng Lan\} and Li, \{Jiang Tao\} and Xiaopeng Li and Zhao, \{Xiao Li\} and Wang, \{Cui Hong\} and Yihua Yu and Wang, \{De Xian\} and Lin Xu and Yang, \{Hai Bo\}",

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doi = "10.1021/ol4032649",

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TY - JOUR

T1 - Unexpected self-assembly of chiral triangles from 90 chiral Di-Pt(II) acceptors

AU - Ou-Yang, Jiang Kun

AU - Zhang, Yan Yan

AU - He, Meng Lan

AU - Li, Jiang Tao

AU - Li, Xiaopeng

AU - Zhao, Xiao Li

AU - Wang, Cui Hong

AU - Yu, Yihua

AU - Wang, De Xian

AU - Xu, Lin

AU - Yang, Hai Bo

PY - 2014/2/7

Y1 - 2014/2/7

N2 - Two unexpected chiral organometallic triangles rather than squares from newly designed 90 chiral di-Pt(II) acceptors were obtained through coordination-driven self-assembly. Their structures were well characterized by multinuclear NMR (1H and 31P) and variable-temperature NMR experiments, ESI-TOF-MS, and elemental analysis. The PM6 semiempirical molecular simulation was employed for the interpretation of the formation and stability of such chiral triangles.

AB - Two unexpected chiral organometallic triangles rather than squares from newly designed 90 chiral di-Pt(II) acceptors were obtained through coordination-driven self-assembly. Their structures were well characterized by multinuclear NMR (1H and 31P) and variable-temperature NMR experiments, ESI-TOF-MS, and elemental analysis. The PM6 semiempirical molecular simulation was employed for the interpretation of the formation and stability of such chiral triangles.

UR - https://www.scopus.com/pages/publications/84893838943

U2 - 10.1021/ol4032649

DO - 10.1021/ol4032649

M3 - 文章

C2 - 24433136

AN - SCOPUS:84893838943

SN - 1523-7060

VL - 16

SP - 664

EP - 667

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

Unexpected self-assembly of chiral triangles from 90 chiral Di-Pt(II) acceptors

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